摘要
用硅酸钠和钼酸钠为原料,在水热条件下合成了一种新的Keggin型多金属氧酸盐[Cu2(phen)4(SiMo12O40)](phen=1,10-邻菲洛啉)(1).通过元素分析、红外光谱分析和X射线单晶衍射对化合物1进行了结构表征,结构表明该化合物属于三斜晶系,P21/c空间群,晶胞参数a=1.303 2(3)nm,b=1.152 2(2)nm,c=2.340 8(8)nm,β=108.29(3)°,V=3.337 3(15)nm3.同时也研究了化合物1的荧光性能.
A novel Keggin-type supramolecular compound,[Cu2(phen)4(SiMo12O40)](1),has been synthesized under hydrothermal conditions and characterized by elemental analysis,IR and single crystal X-ray diffraction.It crystallizes in the triclinic system,space group P21/c,a= 1.303 2(3)nm,b=1.152 2(2)nm,c=2.340 8(8)nm,β=108.29(3)°,V=3.337 3(15)nm3.The fluorescence property of compound(1)was also investigated.
出处
《吉林化工学院学报》
CAS
2012年第3期30-32,共3页
Journal of Jilin Institute of Chemical Technology