摘要
LDHs(layered double hydroxides)是一类结构可调的阴离子层状及插层结构功能材料,近些年来在催化领域得到了广泛的关注.本文综述了有关LDHs材料构筑原则的理论研究、组装方法及其在多相催化领域应用的最新进展.
Layered double hydroxides (LDHs) refer to a large class of anionic clays with diverse brucite-like layers and intercalated structures, which have attracted increasing interests in recent years due to their potential applications as catalysts, catalyst supports and catalyst precursors. This review summeries the latest development of LDH materials in the theoretical criteria for the layered structures, preparation methodology, and their applications as heterogeneous catalytic materials in selective oxidation, acid-base catalyzed, photocatalytic, bio-catalyzed, and asymmetric synthesis reactions.
出处
《中国科学:化学》
CSCD
北大核心
2012年第4期390-405,共16页
SCIENTIA SINICA Chimica
基金
国家自然科学基金
国家重点基础研究发展计划(973计划)(2011CBA00500)
国家高技术研究发展计划(863计划)(2010AA03A403)的资助
“国家杰出青年科学基金”的资助
关键词
阴离子层状材料催化构筑原则组装方法
layered anionic material, heterogeneous catalysis, theoretical criteria, preparation methodology