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异戊醇从氯化物-磷酸体系中萃取磷酸和盐酸 被引量：5

Extraction of phosphoric and hydrochloric acids from the system chlorides-phosphoric acid with isoamyl alcohol
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摘要 研究了异戊醇的萃取性能 ,考察了水相中磷酸和盐酸浓度、金属离子浓度、初始相比与温度等因素对萃取分离性能的影响 。 The extraction behaviors of the title have been studied.It was discovered that the initial phase ratio,temperature,the concentrations of phosphoric and hydrochloric acids as well as the metal ions in the aqueous phase affect extracting process.The most suitable conditions for the extraction are ascertained.
作者 欧阳贻德 刘宏 包传平 金士威
机构地区 武汉化工学院化工系 湖南省资江化学工业学校
出处 《武汉化工学院学报》 2000年第1期4-6,12,共4页 Journal of Wuhan Institute of Chemical Technology
关键词 异戊醇 溶剂萃取 分离 磷酸 盐酸 氯化物 isoamyl alcohol solvent extraction separation phosphoric acid phosphoric acid purification hydrochloric acid
分类号 TQ126.35 [化学工程—无机化工] TQ111.3 [化学工程—无机化工]
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  • 1史德仁.对盐酸法萃取磷酸的技术评价[J].安徽化工,1988,(4):15-21.
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  • 3Yagodin G A,Sergievskii V V. Extraction of phosphoric acid by tributyl phosphate, Zh Neorg Khim,1981,26(6): 1630-1632.
  • 4Zhang Y, Valient M. Muhammed M. Extraction of nitric and phosphoric acids with tributyl phosphate.Solvent Extr Ion Exch,1989,7(2):173-200.
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  • 6尹建平 赵廷仁 陈业清等.S512对磷酸盐酸混合液中磷酸的萃取[J].华中师范大学学报：自然科学版,1988,(1):94-97.

共引文献8

同被引文献30

  • 1欧阳贻德,陈古圣,苏裕光.异戊醇从氧化物-磷酸体系中萃取磷酸的动力学研究[J].化学工程,1997,25(1):27-30. 被引量：6
  • 2Bagnavets N L, Klinskii G D, Kesoyan G A, et al. Kinetics of extraction and re-extraction of phosphoric acid and impurities of sulfuric acid and hydrofluoric acid in centrifugal extractor [J]. Khimicheskaya Tekhnologiya, 2003, (3) : 5-9.
  • 3Baumgartner F, Finsterwalder L. On the transfer mechanism of uranium (Ⅵ) and plutonium (Ⅳ) nitrate in the system nitric acid- water/tributylphosphate-dodecane[J]. J Phys Chem, 1970, 74 (1) : 108-112.
  • 4Davey D E, Cattrall R W, Cardwell T J, et al. The rate of mass transfer of metal chlorides between hydrochloric acid and alkylammonium chloride solutions.Ⅰ.Niobium (Ⅴ) between 10. 8M hydrochloric acid and bis (3,5,5-trimethylhexyl) ammonium chloride in chloroform[J]. J Inorg Nucl Chem, 1978, 40(6):1135- 1140.
  • 5Horner D E, Mailen J C, Coggins J R Jr, et al. Interphase transfer kinetics of thorium between nitric acid and tributyl phosphorate solutions using the single drop and the Lewis cell techniques [J]. Ind Eng Chem Fundam, 1980, 19(3):287-291.
  • 6周祖铭 毛家骏 杨永乐 等.溶剂萃取动力学的研究Ⅱ·三辛基氧化膦从盐酸体系中萃取铀(Ⅳ)的速率.化学学报,1983,41(12):1100-1107.
  • 7Biswas R K, Begum D A. Study of kinetics of forward extraction · of Fe (Ⅲ) from chloride medium by di-2-ethylhexylphosphoric acid in kerosene using the single drop technique[J]. Hydrometallurgy, 1999, 54(1):1-23.
  • 8HORNER D E, MAILEN J C, COGGINS J R Jr, et al. Interphase transfer kinetics of thorium between nitric acid and tributyl phosphorate solutions using the single drop and the Lewis cell techniques [ J ]. Ind Eng Chem Fundam, 1980, 19 ( 3 ) : 287-291.
  • 9BISWAS R K, BEGUM D A. Study of kinetics of forward extraction of Fe (Ⅲ) from chloride medium by di-2- ethylhexylphosphorie acid in kerosene using the single drop technique[ J ]. Hydrometallurgy, 1999, 54( 1 ) : 1-23.
  • 10吕中,陈古圣,苏裕光.溶剂萃取法萃取磷酸的研究[J].无机盐工业,1997,11(6):3-4. 被引量：9

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武汉化工学院学报
2000年 第1期

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