苯乙炔基封端聚苯基喹恶啉的合成与性能研究

Synthesis and Properties of Phenylethynyl-Terminated Polyphenylquinoxalines

以4-苯乙炔基苯偶酰(PEBZ)作为封端剂,以芳香族四酮,9,9-双(4-苯偶酰氧基苯基)芴和芳香族四胺3,3,'4,,4'-四氨基联苯(BPTA)作为单体,设计并合成了一系列苯乙炔基封端聚苯基喹恶啉(PEPPQ)树脂(PPQ-1～PPQ-4)。设计分子量分别为2 500(PPQ-1)、5 000(PPQ-2)、10 000(PPQ-3)以及20 000(PPQ-4)。流变分析表明,PPQ-1与PPQ-2具有良好的加工性能3,50℃左右的最低黏度分别为21和568 Pa.s。通过热模压工艺制备了PPQ-1和PPQ-2固化样件,Tg分别为338和325℃。固化物具有优良的耐热稳定性,氮气中以10℃/min升温5,%失重温度均在550℃以上7,50℃时的残重在60%以上。PPQ-2固化物表现出了良好的力学性能,拉伸与弯曲强度分别为88和155 MPa,断裂伸长率达到7.6%。

A series of phenylethynyl-terminated polyphenylquinoxalines（PEPPQs）（PPQ-1 to PPQ-4） were prepared with 4-phenylethynylbenzil（PEBZ） as the terminator and 99,-bis（4-benziloxyphenyl） fluorene（FLTK） and 33,＇4,4,＇-tetraaminobiphenyl（BPTA） as the monomers.The designed molecular weights are 2 500 for PPQ-1,5 000 for PPQ-2,10 000 for PPQ-3,and 20 000 for PPQ-4.The rheological measurements show that PPQ-1 and PPQ-2 exhibited good processability with the lowest melting viscosities of 21 Pa.s and 568 Pa.s at about 350℃,respectively.Cured PPQ-1 and PPQ-2 samples are prepared via the thermally molding process.The cured PEPPQs show high glass transition temperatures of 338℃ for PPQ-1 and 325℃ for PPQ-2,respectively.The cured PEPPQs show good ther-mal stability with the 5% weight loss temperatures higher than 550℃ and residual weight ratio higher than 60% at 750℃.Cured PPQ-2 resin exhibit good mechanical properties with the tensile and flexural strengths of 88 MPa and 125 MPa,respectively.The elongation at break of the resin reached 7.6%.