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担载型铜-锌催化剂上顺丁烯二酸酐加氢制γ-丁内酯 被引量:9

MALEIC ANHYDRIDE HYDROGENATING TO γ-BL OVER SUPPORTED COPPER CATALYSTS
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摘要 Cu-ZnO/Oxide catalysts wre prepared by deposition which were used for Maleic Anhydride hydrogenating to γ-BL All these catalysts have so good activity and selectivity that these catalysts surpassed one kind of industrial catalyst which was often used in industry The catalyst supported by Al2O3-TiO2 has best activity and selectivity; The catalyst supported by CeO2 has good low-temperature activity which possesses a giant potency for saving energy The results of TPR, XRD and XPS showed that Oxides was the main phases before reducing and only the CuO was reduced to Cu0 Cu0 was the active and the catalyst with good dispersion had good catalytic, such as the catalyst of 50CuO-40ZnO/10(Al2O3-10TiO2) Cu-ZnO/Oxide catalysts wre prepared by deposition which were used for Maleic Anhydride hydrogenating to γ-BL All these catalysts have so good activity and selectivity that these catalysts surpassed one kind of industrial catalyst which was often used in industry The catalyst supported by Al2O3-TiO2 has best activity and selectivity; The catalyst supported by CeO2 has good low-temperature activity which possesses a giant potency for saving energy The results of TPR, XRD and XPS showed that Oxides was the main phases before reducing and only the CuO was reduced to Cu0 Cu0 was the active and the catalyst with good dispersion had good catalytic, such as the catalyst of 50CuO-40ZnO/10(Al2O3-10TiO2)
出处 《燃料化学学报》 EI CAS CSCD 北大核心 2000年第2期189-192,共4页 Journal of Fuel Chemistry and Technology
关键词 沉积法 催化剂 顺丁烯二酸酐 Γ-丁内酯 加氢 deposition, supported catalyst, maleic anhydride, γ-BL, hydrogenation
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