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催化剂制备方法对甘油液相重整制氢反应的影响 被引量：2

Influence of preparation methods of the catalyst on hydrogen production from aqueous-phase reforming of glycerol
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摘要 能源紧缺和环境问题已成为全世界关注的话题,开发利用可再生的清洁能源备受关注,甘油水溶液催化重整制氢是一条资源利用生态化的工艺路线。分别采用共沉淀法和浸渍法制备了NiCoAl复合氧化物催化剂,并采用XRD、比表面积及热分析等对催化剂进行结构表征,结合甘油液相重整制氢中催化剂活性测试结果表明,共沉淀法制得的NiCoAl复合氧化物催化剂的活性较好,较适宜的焙烧温度为550℃。 Great attention to the shortage of energy resources and environmental problems has been paid.Seeking and utilizing renewable and sustainable green energy resources are focused on by human society.It is a technical process of ecological resource utilization to employ glycerol derived from biomass as the raw materials to generate hydrogen by aqueous-phase reforming.For this purpose,NiCoAl complex oxide catalysts were prepared by using co-precipitation and impregnation methods,and the influence of calcination temperature was also investigated.The structural properties of catalysts were characterized by XRD,TG-DTG and BET.The results showed that compared with impregnation method,NiCoAl complex oxide catalyst prepared by co-precipitation method exhibited higher activities for hydrogen production,and the optimum calcination temperature of the catalyst was 550 ℃.
作者 江涛 韩林芯 于恺 董朝辉 王轲 李涛 曹发海
机构地区 华东理工大学化工学院
出处 《工业催化》 CAS 2012年第4期22-25,共4页 Industrial Catalysis
基金 国家高技术研究发展计划(863计划)(2009AA05Z444)资助项目
关键词 催化化学 甘油 液相重整 制氢 NiCoAl复合氧化物催化剂 catalytic chemistry glycerol aqueous-phase reforming hydrogen production NiCoAl complex oxide catalyst
分类号 O643.36 [理学—物理化学] TQ426.6 [化学工程]
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参考文献7

  • 1Cortright R D, Davda R R, Dumesic J A. Hydrogen from cat- alytic reforming of biomass-derived hydrocarbons in liquid water [ J ]. Nature,2002,418 (6901) :964 - 967.
  • 2Huber G W, Cortright R D, Dumesic J A. Renewable alkanes by aqueous-phase reforming of biomass-derived oxygenates [ J ]. Angewandte Chemie, International Edition, 2004, 43 (12) : 1549 - 1551.
  • 3Huber G W, Dumesic J A. An overview of aqueous-phase catalytic processes for production of hydrogen and alkanes in a biorefinery [ J ]. Catalysis Today,2006,111 ( 1/2 ) : 119 - 132.
  • 4Huber G W, Dumesic J A. An overview of aqueous-phase catalytic processes for production of hydrogen and alkanes in a biorefinery[ J]. Catalysis Today,2006,111 (1/2) : 119 - 132.
  • 5Luo N, Cao F, Zhao X, et al. Thermodynamic analysis of aqueous-reforming of polyols for hydrogen generation [ J ]. Fuel ,2007,86( 12/13 ) : 1727 - 1736.
  • 6Luo N, Zhao X, Cao F, et al. Thermodynamic study on hydro- gen generation from different glycerol reforming processes [J]. Energy & Fuels,2007,21 (6) :3505 - 3512.
  • 7Luo N, Ouyang K, Cao F, et al. Hydrogen generation from liquid reforming of glycerin over Ni-Co bimetallic catalyst [ J]. Biomass and Bioenergy,2010,34:489 -495.

同被引文献19

  • 1Copeland J, Foo G, Harrison L, et al. In Situ ATR-IR Study on Aqueous Phase Reforming Reactions of Glycerol over a Pt/ γ-A1203 Catalyst [J]. Catal Today, 2013, 205 (30) : 49 - 59.
  • 2Adhikari S, Femando S D, Filip T, et al. Conversion of Glyc- erol to Hydrogen via a Steam Reforming Process over Nickel Catalysts [ J ]. Energy Fuels, 2008, 22 (2) : 1220 - 1226.
  • 3Fermoso J, Li He, De Chen. Production of High Purity Hydro- gen by Sorption Enhanced Steam Reforming of Crude Glycerol [J].lntJHydrogenEnergy, 2012, 37(19) : 14047- 14054.
  • 4Sanchez E A, D'Angelo M A, Comelli R A. Hydrogen Produc- tion from Glycerol on Ni/A1203 Catalyst [J]. Int J Hydrogen Energy, 2010, 35 (11) : 5902 - 5907.
  • 5Guo Yong, Liu Xiaohui, Azmat M U, et al. Hydrogen Produc- tion by Aqueous-Phase Reforming of Glycerol over Ni-B Cata- lysts[J]. IntJHydrogenEnergy, 2012, 37(1): 227-234.
  • 6Sanchez E A, Comelli R A. Hydrogen by Glycerol Steam Re- forming on a Nickel-Alumina Catalyst: Deactivation Processes and Regeneration [J]. lnt J Hydrogen Energy, 2012, 37(19): 14740- 14746.
  • 7Adhikari S, Femando S, Haryanto A. A Comparative Thermo- dynamic and Experimental Analysis on Hydrogen Production by Steam Reforming of Glycerin [J]. Energy Fuels, 2007, 21 (4) : 2306 - 2310.
  • 8Adhikari S, Fernando S, Haryanto A. Production of Hydrogen by Steam Reforming of Glycerin over Alumina-Supported Metal Catalysts[J].CatalToday, 2007, 129(3/4): 355-364.
  • 9Hirai T, lkenagaN O, Miyake T, et al. Production of Hydro- gen by Steam Reforming of Glycerin on Ruthenium Catalyst[J].EnergyFuels, 2005, 19(4) : 1761 - 1762.
  • 10Zhang Baocai, Tang Xiaolan, Li Yong, et al. Hydrogen Pro- duction from Steam Reforming of Ethanol and Glycerol over Ceria-Supported Metal Catalysts [J]. lnt JHydrogen Energy, 2007, 32(13): 2367-2373.

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工业催化
2012年 第4期

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