不对称卟啉配体及其锌配合物的合成与电化学性质

Synthesis and Electrochemical Property of an Unsymmetrical Porphyrin and Its Zn Compound

采用直接缩合法合成了新型含有肽键的不对称5-[4-(3,5-二-十二烷氧基苯甲酰亚胺基)苯基]-10,15,20-三苯基卟啉配体(DDTPP)及其锌配合物(DDTPPZn),并通过元素分析、紫外-可见光谱、红外光谱和核磁共振氢谱等测试方法对化合物的结构进行确认,利用循环伏安法研究了其电化学性质.

A new 5-[4-（3,5-dicetyloxybenzoylamino）phenyl]-10,15,20-triphenylporphyrin（DDTPP） and its relative zinc compound（DDTPPZn） were synthesized and characterized by means of elemental analyses,UV-Vis,IR and 1H NMR spectroscopies.Furthermore,and the oxidation and reduction properties of the compounds were studied by the cyclic voltammetry,and the oxidation-reduction potentials were obtained.