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Transformation character of ferrite formation by a ledge mechanism under a mixed-control model

Transformation character of ferrite formation by a ledge mechanism under a mixed-control model
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摘要 A mixed-control model was developed to study the transformation character of ferrite formation by a ledge mechanism. A nu- merical two-dimensional diffusion-field model was combined to describe the evolution of the diffusion field ahead of the migrating austenite/ferrite interface. The calculation results show that the bulk diffusion-controlled model leads to a deviation from experimental results under large solute supersaturation. In the mixed-control model, solute supersaturation and a parameter Z together determine the transformation character, which is quantified by the normalized concentration of carbon in austenite at the austenite/ferfite interface. By comparing with experimental data, thepre-exponential factor of interface mobility, M0, is estimated within the range from 0.10 to 0.60 mol-m·J^-1·s^-1 for the alloys with 0.1 lwt%-0.49wt% C at 700-740℃. For a certain Fe-C alloy, the trend of the transformation character relies on the magnitude of M0 as the transformation temperature decreases. A mixed-control model was developed to study the transformation character of ferrite formation by a ledge mechanism. A nu- merical two-dimensional diffusion-field model was combined to describe the evolution of the diffusion field ahead of the migrating austenite/ferrite interface. The calculation results show that the bulk diffusion-controlled model leads to a deviation from experimental results under large solute supersaturation. In the mixed-control model, solute supersaturation and a parameter Z together determine the transformation character, which is quantified by the normalized concentration of carbon in austenite at the austenite/ferfite interface. By comparing with experimental data, thepre-exponential factor of interface mobility, M0, is estimated within the range from 0.10 to 0.60 mol-m·J^-1·s^-1 for the alloys with 0.1 lwt%-0.49wt% C at 700-740℃. For a certain Fe-C alloy, the trend of the transformation character relies on the magnitude of M0 as the transformation temperature decreases.
出处 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2012年第5期428-433,共6页 矿物冶金与材料学报(英文版)
基金 supported by the National Natural Science Foundation of China (Nos.51171087 and 51071089) the Specialized Research Fund for the Doctoral Program of Higher Education (No.20070003006)
关键词 iron carbon alloys modeling FERRITE ledge mechanism diffusion INTERFACES iron carbon alloys modeling ferrite ledge mechanism diffusion interfaces
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