期刊文献+

表面包覆Co(OH)_2和Er(OH)_3的球形Ni(OH)_2的高温性能

High-temperature performances of spherical Ni(OH)_2 coated with Co(OH)_2 and Er(OH)_3
下载PDF
导出
摘要 利用化学沉淀法在球形Ni(OH)2表面复合包覆Co(OH)2和Er(OH)3,利用XRD、SEM和恒电流充放电技术测试其结构、表面微观形貌和充放电性能。研究不同包覆量对其常温和高温性能的影响,确定最佳包覆比为1%(质量分数)。循环伏安测试结果表明:包覆Er(OH)3的球形Ni(OH)2可以有效提高镍正极在高温环境下的析氧副反应电位,从而抑制析氧副反应的发生,最终提高镍电极在高温环境下的充电效率和活性物质利用率。 The spherical nickel hydroxide coated by Co(OH)2 and Er(OH)3 was prepared by chemical precipitation.The structure,surface microstructures and charge-discharge properties were analyzed by X-ray diffractometry,scanning electron microscopy and galvanostatic charge-discharge cycling technology.The optimum coating amount of was determined to be 1%(mass fraction) by comparing different amounts of coating on their electrochemical properties at room temperature and high temperature.The cyclic voltammetry results indicate that the coating of the erbium hydroxide on the spherical nickel hydroxide can enhance the potential of oxygen evolution at high temperature,and thus inhibit the occurrence of oxygen evolution.Simultaneously,the charge efficiency and the active material utilization of nickel hydroxide electrode are increase at high temperature.
出处 《中国有色金属学报》 EI CAS CSCD 北大核心 2012年第4期1142-1146,共5页 The Chinese Journal of Nonferrous Metals
基金 内蒙古自然科学基金资助项目(2012MS02) 内蒙古自治区高等学校科学研究项目(NJZZ12101) 包头市科技计划项目(2011Z1006) 内蒙古自治区专利转化计划项目
关键词 球形NI(OH)2 充放电性能 高温性能 Er(OH)3 包覆 spherical nickel hydroxide charge-discharge properties high-temperature performance erbium hydroxide coating
  • 相关文献

参考文献16

  • 1RAMESH T N,JAYASHREE R S,VISHNU KAMATH P.Effectof lightweight supports on specific discharge capacity ofβ-nickelhydroxide[J].Journal of Power Sources,2002,104:295-298.
  • 2RAMESH T N,VISHNU KAMATH P.Synthesis of nickelhydroxide:Effect of precipitation conditions on phase selectivityand structural disorder[J].Journal of Power Sources,2006,156:655-661.
  • 3SHUKLA A K,VENUGOPALAN S,HARIPRAKASH B.Nickel-based rechargeable batteries[J].Journal of Power Sources,2001,100:125-148.
  • 4MI X,GAO X P,JIANG C Y,GENG M M,YAN J,WAN C R.High temperature performances of yttrium doped sphericalnickel hydroxides[J].Electrochimica Acta,2004,49(20):3361-3366.
  • 5刘建华,王丹,刘圣迁,冯雪冰.正交实验法提高MH/Ni电池的高温性能[J].电池,2003,33(4):218-220. 被引量:12
  • 6米欣,姜长印,耿鸣明,阎杰,高学平,万春荣.掺钇球形Ni(OH)_2的合成及高温性能研究[J].电池,2004,34(1):13-15. 被引量:11
  • 7FAN Jing,YANG Yi-fu,YU Peng,SHAO H.Effects of surfacecoating of Y(OH)3 on the electromechemical performance ofspherical Ni(OH)2[J].Journal of Power Sources,2007,171:981.
  • 8任俊霞,周震,阎杰.Y掺杂对氢氧化镍电极高温性能的影响[J].物理化学学报,2007,23(5):738-742. 被引量:10
  • 9HE Xiang-ming,WANG Li,LI Wen,JIANG Chang-yin,WANChun-rong.Ytterbium coating of spherical Ni(OH)2 cathodematerials Ni-MH batteries at elevated temperature[J].Journal ofPower Sources,2006,158:1480-1483.
  • 10李稳,姜长印,万春荣.表面包覆Yb(OH)_3的球形氢氧化镍的高温性能研究[J].无机材料学报,2006,21(1):121-127. 被引量:5

二级参考文献52

  • 1吴梅银,王建明,张鉴清,曹楚南.掺锰氢氧化镍的结构与电化学性能(英文)[J].物理化学学报,2005,21(5):523-527. 被引量:17
  • 2任俊霞,王小建,李宇展,高学平,阎杰.Lu_2O_3对球形Ni(OH)_2高温充放电性能的影响[J].中国稀土学报,2005,23(2):195-199. 被引量:4
  • 3于涛,翟玉春,阎永恒,周时国.镍电极掺杂[x(Y_2O_3)+y(Er_2O_3)]的MH/Ni电池性能研究[J].稀土,2006,27(5):20-23. 被引量:6
  • 4樊晓光,吴伯荣,朱磊,简旭宇,陈晖.复合添加Lu_2O_3和Er_2O_3对镍氢电池Ni(OH)_2正极高温性能的影响[J].稀有金属,2007,31(1):81-85. 被引量:10
  • 5Bronoel G, Reby J. Mechanism of oxygen evolution in basic medium at a nickel electrode [J]. Electrochimica Acta, 1980, 25: 973.
  • 6Snook G A, Duffy N W, Pandolfo A G. Evaluation of the effects of oxygen evolution on the capacity and cycle life of nickel hydroxide electrode materials [J]. J. Power Sources, 2007, 168: 513.
  • 7Nan Junmin, Hou Xianlu, Yang Minjie, Han Dongmei, Li Weishan. Effect of rare-earth elements on the temperature performances of power nickel-metal hydride batteries for electric tools [J]. J. Electrochem. Soc., 2006, 153(6): A1159.
  • 8Mi Xin, Gao Xueping, Jiang Changyin, Geng Mingming, Yan Jie, Wan Chunrong. High temperature performances of yttriumdoped spherical nickel hydroxide [ J ]. Electrochimica Acta, 2004, 49: 3361.
  • 9Fan Jing, Yang Yifu, Yu Peng, Chen Weihua, Shao Huixia. Effects of surface coating of Y(OH)3 on the electrochemical performance of spherical Ni ( OH)2 [ J ]. J. Power Sources, 2007, 171 : 981.
  • 10He Xiangming, Wang Li, Li Wen, Jiang Changyin, Wan Chuntong. Ytterbium coating of spherical Ni(OH)2 cathode materials for Ni-MH batteries at elevated temperature [J]. J. Power Sourees, 2006, 158: 1480.

共引文献34

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部