摘要
A novel Co(phen)2/C catalyst was prepared by coating cobalt(II) phenanthroline (phen) chelate on BP2000 carbon black and then heat treating in an inert atmosphere. The obtained Co(phen)2/C product with 1.0 wt% cobalt loading exhibits similar morphology and porosity characteristics to those of the bare BP2000. X-ray diffraction measurements demonstrate a face-centered cubic (fcc) α-Co phase embedded in the carbon support after pyrolysis. Charge/discharge tests of the lithium-oxygen cells using the prepared Co(phen)2/C catalyst show high discharge capacities of 4870 mAh g-1 (0.05 mA cm-2 ), 3353 mAh g-1 (0.1 mA cm-2 ) and 3220 mAh g 1 (0.15 mA cm-2 ), respectively. The Co(phen) 2 /C cathode exhibits reasonable reversibility with capacity retention of 1401 mAh g-1 ( 0.1 mA cm-2 ) after 10 cycles. The superior electrochemical performance of the prepared Co(phen)2/C catalyst and low cost of the phenanthroline chelating agent indicate that Co(phen)2/C is a promising cheap catalyst for lithium-air batteries.
A novel Co（phen）2/C catalyst was prepared by coating cobalt（II） phenanthroline （phen） chelate on BP2000 carbon black and then heat treating in an inert atmosphere. The obtained Co（phen）2/C product with 1.0 wt% cobalt loading exhibits similar morphology and porosity characteristics to those of the bare BP2000. X-ray diffraction measurements demonstrate a face-centered cubic （fcc） α-Co phase embedded in the carbon support after pyrolysis. Charge/discharge tests of the lithium-oxygen cells using the prepared Co（phen）2/C catalyst show high discharge capacities of 4870 mAh g^-1 （0.05 mA cm^-2 ）, 3353 mAh g^-1 （0.1 mA cm^-2 ） and 3220 mAh g ^-1 （0.15 mA cm^-2 ）, respectively. The Co（phen） 2 /C cathode exhibits reasonable reversibility with capacity retention of 1401 mAh g^-1 （ 0.1 mA cm^-2 ） after 10 cycles. The superior electrochemical performance of the prepared Co（phen）2/C catalyst and low cost of the phenanthroline chelating agent indicate that Co（phen）2/C is a promising cheap catalyst for lithium-air batteries.
基金
supported by the National Natural Science Foundation of China (21073120, 20976104 and 21006063)
the Special Funds for the Major State Basic Research Project of China (2007CB209705)
the Science and Technology Commission of the Shanghai Municipality (09dz1203603,10dz1202702)
