期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

二羟基二过碘酸合镍(Ⅳ)氧化还原引发丙烯酰胺聚合反应动力学的研究 被引量：15

STUDY ON THE KINETICS OF ACRYLAMIDE POLYMERIZATION INITIATED BY DIPERIODATONICKELATE (Ⅳ) PERIODATE COMPLEX
下载PDF
导出
摘要 The kinetics of acrylamide (AAM) polymerization initiated by diperiodatonickelate(Ⅳ) periodate complex was studied in aqueous alkaline medium.The results indicate that the equation of the polymerization rate is as follows:R p=k[Ni(Ⅳ)] 0 72 [AM] 1 41 and the overall activation energy of AAM polymerization is 41 33kJ/mol.The polymer molecular weight decreases with increasing [Ni(Ⅳ)] and increases with increasing [AAM].The effects of various reaction conditions on the polymerization rate were also studied.The initiation mechanism was proposed. The kinetics of acrylamide (AAM) polymerization initiated by diperiodatonickelate(Ⅳ) periodate complex was studied in aqueous alkaline medium.The results indicate that the equation of the polymerization rate is as follows:R p=k[Ni(Ⅳ)] 0 72 [AM] 1 41 and the overall activation energy of AAM polymerization is 41 33kJ/mol.The polymer molecular weight decreases with increasing [Ni(Ⅳ)] and increases with increasing [AAM].The effects of various reaction conditions on the polymerization rate were also studied.The initiation mechanism was proposed.
作者 刘盈海 商亚娟 李卫平 王辰红 邓奎林
机构地区 河北大学化学系
出处 《高分子学报》 SCIE CAS CSCD 北大核心 2000年第2期235-238,共4页 Acta Polymerica Sinica
关键词 镍有机化合物 聚合反应动力学 丙烯酰胺 Diperiodatonickelate(Ⅳ),Acrylamide,Redox initiation
分类号 O631 [理学—高分子化学]
  • 相关文献

参考文献3

二级参考文献20

  • 1伯顿·克拉克.高等教育系统[M].杭州:杭州大学出版社,1994.279,178.
  • 2Verne A. Stadtman, etc. Berkeley At Mid-Century :Elements of a Golden Age[M], Berkeley Public Policy Press.2002. 3.
  • 3Roger Geiger. Research and Relevant Knowledge: American Research Universities Since World War Ⅱ[M]. Oxford University Press. 1993. 74.
  • 4Verne A. Stadtman, etc. Berkeley At Mid-Century :Elements of a Golden Age[M]. Berkeley Public Policy Press.2002. 69.
  • 5Arthur Levine. Higher Learning in America[M]. The John Hopkins University Press. 1993. 116.
  • 6Abraham Flexner. Daniel Coil Gilman : Creator of the American Type of University[M]. Harcourt ,Brace and Company ,Inc. 1976. 13.
  • 7Verne A. Stadtman, etc. Berkeley At Mid-Century :Elements of a Golden Age[M]. Berkeley Public Policy Press.2002. 2.
  • 8Roger Geiger. To Advance Knowledge: The Growth of American Research Universities: 1900-1940[M]. Oxford University Press. 1986. 211.
  • 9Roger Geiger. Research and Relevant Knowledge: American Research Universities Since World War Ⅱ[M]. Oxford University Press. 1993. 76.
  • 10Roger Geiger. Research and Relevant Knowledge: American Research Universities Since World War Ⅱ [M]. Oxford University Press. 1993. 73.

同被引文献99

引证文献15

二级引证文献28

高分子学报
2000年 第2期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部