摘要
为探索Gd2Zr2O7烧绿石快速固化高放废物中锕系核素的新途径,实验用高温高压固相反应法在3～4GPa压力、1 573～1 673K温度范围内合成了Gd1.6Nd0.4Zr2O7烧绿石固化体,并利用X射线衍射仪、扫描电镜对样品进行了分析。结果表明:高温高压固相反应法可在极短时间(15min)内合成完全固溶的Gd1.6Nd0.4Zr2O7立方烧绿石固化体,较常用制备方法(一般合成时间不低于48h)快近200倍;用该技术合成的样品在常温常压下的相转变温度及压力得以显著提高,烧绿石相更趋稳定;样品晶格常数随Nd含量的增加及合成温度的升高而逐渐增大,随合成压力的增加而逐渐减小。这种快速高效的合成方法为未来开展高放核素的工业固化提供了一种新的技术途径和基本数据参考。
In order to explore a rapid synthesis method for Gd2Zr2O7 pyrochlore immobilizing actinide elements from radioactive wastes,Gd1.6Nd0.4Zr2O7 pyrochlore was synthesized via solid-state reactions for 15 min under high pressure（3-4 GPa） and high temperature（1 573-1 673 K）.The products were characterized by powder X-ray diffraction and scanning electron microscopy.The results indicate that among all the compositions,Gd1.6Nd0.4Zr2O7 solid solution with a cubic pyrochlore structure is synthesized within only 15 min.This period is approximate 200 times faster than other common preparation methods with synthesis time of not less than 48 h.The phase transition pressure and temperature of the samples are expanded under high pressure and temperature conditions.The stability of the pyrochlore phase is found to increase.The lattice parameters of Gd1.6Nd0.4Zr2O7 solid solutions gradually increase with the neodymium content and the synthesis temperature,and decrease with the increase of the synthesis pressure.
出处
《原子能科学技术》
EI
CAS
CSCD
北大核心
2012年第4期390-395,共6页
Atomic Energy Science and Technology
基金
国家自然科学基金资助项目(51074131)
国防基础科研计划资助项目(B3120110001)
关键词
Gd2Zr2O7烧绿石
高温高压
高放废物固化
Gd2Zr2O7 pyrochlore
high temperature and high pressure
high-level waste immobilization
