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配合物｛[Zn(HFlu)_2(CHO_2)]·NO_3｝_n的合成、表征及其晶体结构

Synthesis,Characterization,Crystal Structure of a New Zinc(Ⅱ) Coordination Complexes of Fluconazol
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摘要 用水热合成法以硝酸锌、氟康唑(HFlu)、甲酸为原料合成了一种新颖的配合物,利用单晶X射线、元素分析、等对配合物进行了表征.单晶X射线衍射分析的结果表明:标题化合物属于三斜晶系,空间群为P-1,晶胞参数为a=10.503(10),b=11.745(11),c=14.122(13),α=90.808(11),β=105.841(11),γ=101.996(11).锌采用六配位的模式,且位于变形的八面体中心,每个锌原子分别与4个各异氟康唑上的三氮唑[Zn-N=2,156(2)]的4-号氮原子以及两个甲酸根[Zn-O=2.086(2)或者是2.137(5)]进行配位. A coordination polymer containing divalent zinc,fluconazole,formic acid radical has been obtained by hydrothermal method.Its structure was determined by means of single-crystal X-ray diffraction analysis with the following crystal data：triclinic space group P-1,a = 10.503（10） ,b = 11.745（11） ,c= 14.122（13） ,α= 90.808（11） ,β= 105.841（11） ,γ= 101.996（11） .The mode of Zinc was Six coordination and located the center of distortion octahedral,Each zinc center was coordinated to four triazole nitrogen[Zn-N=2,156（2） ] atoms from distinct fluconazole ligands and a pair of formic acid radical[Zn-O=2.086（2）  or.137（5） ].
作者 王代银 罗伟强 汤金牛 安永鹏
机构地区 广西民族大学化学化工学院
出处 《广西民族大学学报（自然科学版）》 CAS 2012年第1期84-87,共4页 Journal of Guangxi Minzu University ：Natural Science Edition
基金 广西自然科学基金(0832080) 广西民族大学研究生教育创新计划项目(gxun-chx2011085)
关键词 晶体结构 氟康唑 锌 配位聚合物 crystal structure fluconazole Zinc coordination polymer
分类号 O614 [理学—无机化学]
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参考文献15

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广西民族大学学报（自然科学版）
2012年 第1期

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