期刊文献+

高压脉冲电场对不同乳酸乙醇反应体系的影响 被引量:2

Non-Thermal Effect of Pulsed Electric Field on Esterification of Lactic Acid with Ethanol
下载PDF
导出
摘要 研究不同处理时间、醇酸比条件下脉冲电场(PEF)处理对乳酸和乙醇酯化反应的影响,并分析PEF处理高电导率反应体系的热效应和非热PEF效应。结果表明,同一场强、反应温度、反应时间条件下,随着流速的逐渐增大,单次PEF处理时间缩短,乳酸乙酯的生成量逐渐减少。同一电导率条件下,PEF处理醇酸比由物质的量的比0.5:1增大至2:1的4个反应体系中,随着醇酸比的增大,乳酸乙酯的生成量也逐渐增加。反应10h内,PEF处理高电导率反应体系对反应的促进效果中非热效应促进效果最高可达总反应效果的69.4%。 The effect of pulsed electric field(PEF) treatment under varying conditions of treatment time,flow rate and ethanol/lactic acid ratio on esterification between lactic acid and ethanol was investigated in this study.Meanwhile,the thermal effect and non-thermal effects of PEF treatment were also compared.The results indicated that the reaction was enhanced with decreasing flow rate or increasing single treatment time.When the molar ratio between ethanol and lactic acid was increased from 0.5:1 to 2:1,the yield of ethyl lactate was increased gradually.The non-effect of PEF treatment on esterification accounted for 69.4% of the total effect within 10 h.
出处 《食品科学》 EI CAS CSCD 北大核心 2012年第9期64-67,共4页 Food Science
基金 国家自然科学基金项目(21076088) 广东省自然科学基金项目(9151008901000159)
关键词 脉冲电场 乳酸乙酯 酯化反应 醇酸比 电导率 pulsed electric field ethyl lactate esterification ethanol/lactic acid molar ratio electric conductivity
  • 相关文献

参考文献15

  • 1WASEWAR K, PATIDAR S, AGARWAL V K. Esterification of lactic acid with ethanol in a pervaporation reactor: modeling and performance study[J]. Desalination, 2009, 243(1/3): 305-313.
  • 2PEREIRA P S M, SILVA V M TM, PINHO S P, et al. Bath and continuous studies for ethyl lactate synthesis in a pervaporation mem- brane r~actor[J]. Journal of Membrane Science, 2010, 361: 43-55.
  • 3张小曼.离子液体催化合成食用香料乳酸乙酯的研究[J].化学工程师,2010,24(1):58-60. 被引量:5
  • 4王欣,宋航,许超,李江,杜开峰.响应面法优化离子液体催化合成乳酸乙酯[J].化工进展,2009,28(6):1032-1035. 被引量:4
  • 5DELGADO P, SANZ M T, BELTRAN S. Kinetic study for esterifica- tion of lactic acid with ethanol and hydrolysis of ethyl lactate using an ion-exchange resin catalyst[J]. Chemical Engineering Journal, 2007, 126(2/3): 111-118.
  • 6邓斌,余瑞金,陈六平,俞秋.稀土复合固体超强酸SO_4^(2-)/ZrO_2-CeO_2催化合成食用香料乳酸乙酯的研究[J].食品与发酵工业,2008,34(6):62-64. 被引量:9
  • 7HUANG Zhihong, GAO Jing, ZHAO Tiantao, et al. Lipase catalyzed synthesis of ethyl lactate[C]//2009 3International Conference on Bioinformatics and Biomedical Engineering. Beijing: IEEE Engineer- ing in Medicine and Biology Society, 2009: 4190-4193.
  • 8赵天涛,张丽杰,高静,黄志红,全学军.脂肪酶催化乳酸与乙醇合成乳酸乙酯的反应动力学[J].催化学报,2008,29(2):141-144. 被引量:15
  • 9PUETROLAA E, LOPEZ N, CONDON S, et al. Potential applications of PEF to improve red wine quality[J]. Trends in Food Science & Technology, 2010, 21(5): 247-255.
  • 10ZENG Xinan, YU Shujuan, ZHANG Lu, et al. The effects of AC electric field on wine maturation[J]. Innovative Food Science and Emerging Technologies, 2008, 9(4): 463-468.

二级参考文献56

共引文献48

同被引文献15

引证文献2

二级引证文献4

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部