摘要
A series of new silicon-containing poly（p-arylene vinylene）s （PAVs） with anthracene units in the main chain were synthesized by hydrosilylation reaction. The introduction of organosilicon units improved the solubility of the polymers, and the π-π conjugation of polymeric chains was interrupted. These polymers behaved as blue-green light emitters with their fluorescence maximum at 447-499 nm and quantum yields in the range of 0.28-0.30 in solution.
A series of new silicon-containing poly（p-arylene vinylene）s （PAVs） with anthracene units in the main chain were synthesized by hydrosilylation reaction. The introduction of organosilicon units improved the solubility of the polymers, and the π-π conjugation of polymeric chains was interrupted. These polymers behaved as blue-green light emitters with their fluorescence maximum at 447-499 nm and quantum yields in the range of 0.28-0.30 in solution.
基金
supported by the National Natural Science Foundation of China(Nos.50673094 and 20774102)
