期刊文献+

2,2-二硝基丙醇最新合成进展及其应用 被引量:4

Latest Synthesis Progress of 2,2-Dinitropropanol and Its Application
下载PDF
导出
摘要 综述了氧化硝化法、氯化硝化法、铁氰化钾路线、电化学法等合成2,2–二硝基丙醇(DNPOH)的进展,并且比较了它们的特点,最后提出了洁净的电化学法是很有前途的绿色合成方法。另外,简述了DNPOH作为关键中间体在合成含能增塑剂和含能黏合剂中的应用情况。 The progress in synthesis of 2,2-dinitropropanol (DNPOH) by oxidative nitrating method, chlorinating nitrating method, potassium ferricyanide route and electrochemical method is reviewed, and their characteristics are compared. At last, it is pointed out that the clean electrochemical method is a promising green synthesis method. In addition, the application situations of DNPOH as a key intermediate in synthesis of energetic plasticizers and binders are briefly described.
机构地区 黎明化工研究院
出处 《化学推进剂与高分子材料》 CAS 2012年第3期32-36,42,共6页 Chemical Propellants & Polymeric Materials
关键词 2 2-二硝基丙醇(DNPOH) 氧化硝化 铁氰化钾 电化学 含能材料 2,2-dinitropropanol (DNPOH) oxidative nitration potassium ferricyanide electrochemistry energeticmaterial
  • 相关文献

参考文献37

  • 1Kurt Baum, Phillip T Berkowitz, Vytautas Grakauslas, et al. Synthesis of electron-deficient oxetanes, 3-azidooxetane, 3,3-dinitrooxetane[J]. J O 2 953-2 956. 3-nitrooxetane, and rg Chem, 1983, 48:.
  • 2姬月萍,李普瑞,汪伟,兰英,丁峰.含能增塑剂的研究现状及发展[J].火炸药学报,2005,28(4):47-51. 被引量:87
  • 3Fan I Y, Vita R, Fine D H. C-nitro compounds: a new class of nitrosating agents[J]. Toxicol Lett, 1978, 2(1): 5-10.
  • 4Fridman A L, Kremleva O B, Zalesov V S. Syn- thesis and study of the physiological activity of aliphatic nitro compounds. XII. Relation among structure, toxicity, and bacteriostatic activity in a series of beta-nitro alcohols[J]. Khim-Farm Zh, 1977, 11(1): 73-75.
  • 5Kaplan R B, Shechter H. A new general reaction for preparing gem dinitro compounds: oxida- tive nitration[J]. J Am Chem Soc, 1961, 83(16): 3 535-3 536.
  • 6Hamel E E, Dehhn J S, Love J A, et al. Synthesis of 2,2-dinitropropanol[J]. Ind Eng Chem Prod Res Dev, 1962, 1(2): 108-116.
  • 7Renato Rindone, Donald A Geiss Jr, Hitoshi Miyoshi. BDNPA/BDNPF shows long-term aging stability[C]//Insensitive Munitions and Energetic Materials Technology Symposium, 2000: 254-274.
  • 8Vytautas Grakauskas, Garver Lee C, Baum Kurt. Catalyzed oxidative nitration of nitration salts[J]. J Org Chem, 1985, 50:1 699-1 702.
  • 9Vytautas Grakauskas, Garver Lee C, Baum Kurt. Synthesis of geminal dinitro compounds: US, 4774336[P]. 1988.
  • 10Vytautas Grakauskas, Garver Lee C, Baum Kurt. Synthesis of geminal dinitro compounds: US, 4910322[P]. 1990.

二级参考文献107

  • 1黄辉,蒋小华,黄毅民.挤注炸药的爆轰性能[J].爆炸与冲击,2005,25(1):70-73. 被引量:3
  • 2姬月萍,李普瑞,汪伟,兰英,丁峰.含能增塑剂的研究现状及发展[J].火炸药学报,2005,28(4):47-51. 被引量:87
  • 3王文浩,周集义.BDNPA/F增塑剂的合成及其发展[J].含能材料,2007,15(1):90-93. 被引量:14
  • 4陈斌,张志忠,姬月萍.偕二硝基类含能增塑剂的合成及应用[J].火炸药学报,2007,30(2):67-70. 被引量:19
  • 5Kaplan R B, Shechter H. A new general reaction for preparing gem-dinitro compounds: Oxidative nitration [J]. JAm Chem Soc, 1961, 83(16): 3535-3536.
  • 6Eugene Guccione. Polaris gets improved fuel from new nitroplasticizers[J]. Chem Eng, 1963(7): 62-64.
  • 7Grakauskas Vytautas, Garver Lee C, Baum Kurt. Catalyzed oxidative nitration of nitronate salts[J]. J Org Chem, 1985, 50:1699-1 702.
  • 8Grakauskas Vytautas, Garver Lee C, Baum Kurt. Synthesis ofgeminal dinitro compounds: US, 4774336 [P]. 1988.
  • 9Grakauskas Vytautas, Garver Lee C, Baum Kurt. Synthesis ofgeminal dinitro compounds: US, 4910322 [P]. 1990.
  • 10Hamilton R Scott, Wardle Robert B. Synthesis ofbis (2,2-dinitropropyl) acetal(BDNPA): US, 5648556[P]. 1997.

共引文献119

同被引文献38

  • 1姬月萍,李普瑞,汪伟,兰英,丁峰.含能增塑剂的研究现状及发展[J].火炸药学报,2005,28(4):47-51. 被引量:87
  • 2王昕.绿色火炸药及相关技术的发展与应用[J].火炸药学报,2006,29(5):67-71. 被引量:33
  • 3吕汝信.从欧洲水下防务展看鱼雷发展趋势[J].鱼雷技术,2007,15(2):8-11. 被引量:6
  • 4陈斌,张志忠,姬月萍.偕二硝基类含能增塑剂的合成及应用[J].火炸药学报,2007,30(2):67-70. 被引量:19
  • 5钟一鹏,等.国外炸药性能手册[M].北京:兵器工业出版社,1988.38-65.
  • 6Gore G M. BDNPA/F as energetic plasticizer inpropellant formulations[C]//29th InternationalAnnual Conference of the ICT, 1998: 136/1-136/12.
  • 7Sato Junichi, Shibuya Miki. Explosive proper-ties of urethane-based PBXs containing HMXand BDNPA/F. I. Effects of HMX contents andits particle size[J]. Kogyo Kayaku, 1992, 53(2):59-66.
  • 8Gore G M, Tipare K R. Studies on effect of incor-poration of BDNPF/A on burning rates of RDX/AP/A1 filled CMDB propellants[J]. Journal of En-ergetic Materials, 2002,20: 255-278.
  • 9Donald Geiss A. Development of IM grenadesubmunitions[C]//NDIA 2003 IM/EM TechnologySymposium. Miami, FL: 2003.
  • 10Van Biert Keith, Geiss Donald A Jr. Insensitiveexplosives for high speed loading applications:US, 6783615[P]. 2004.

引证文献4

二级引证文献12

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部