期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

超声辐照水体系下羟基自由基的检测 被引量：2

Determination of Hydroxyl Free Radicals in Aqueous Solution by Ultrasonic Radiation
下载PDF
导出
摘要 Fricke溶液在低频超声波辐照下产生羟基自由基,产生的羟基自由基可将溶液中的Fe2+氧化为Fe3+,用紫外-可见分光光度法测定Fricke溶液在235nm处的吸光度,根据吸光度变化值ΔA间接测定羟基自由基的产生量。初步研究了超声辐照时间、温度、频率和超声方式等因素对羟基自由基产量的影响。 The hydroxyl free radical, · OH, was produced in Fricke solution under ultrasonic radiation with low frequency, and Fe2＋ was oxidized to Fe3＋ by the hydroxyl free radical in the solution. The output of hydroxyl free radicals in Fricke solution was determined indirectly by measuring the change of absorbance （△A） at 235 nm by UV-Vis spectrophotometry. Influential factors on the output of hydroxyl free radicals, including time of ultrasonic radiation, temperature, frequency and mode of ultrasonic treatment, were preliminarily studied.
作者 洪喆 付朝阳
机构地区 华中科技大学化学与化工学院
出处 《理化检验（化学分册）》 CAS CSCD 北大核心 2012年第5期524-525,529,共3页 Physical Testing and Chemical Analysis(Part B:Chemical Analysis)
关键词 超声辐照 羟基自由基 Fricke溶液 Ultrasonic radiation Hydroxyl free radicals Fricke solution
分类号 O657.32 [理学—分析化学]
  • 相关文献

参考文献5

二级参考文献22

  • 1赵逸云,冯若,鲍慈光,徐克利.声化学反应器研究进展[J].应用声学,1994,13(2):44-48. 被引量：16
  • 2《化学通报》网络版(ChemistryOnline)2006年第2期论文摘要[J].化学通报,2006,69(2):158-160. 被引量：54
  • 3J. E. Kennedy, High-intensity focused ultrasound in the lreatment of solid turnouts[J]. Nat. Rev. Cancer, 2005, 5 (4) : 321-327.
  • 4C. R.Thomas, C. H. Farny, C. C. Coussios, R. A. Roy, Dynamics and control of cavitation during high intensity focused ultrasound application[J]. Acoust. Res. Lett, 2005, 6 (3) : 182-187.
  • 5Hang Chen, Xiaojing Li, Mingxi Wan. Spatial temporal dynamics of cavitation bubble clouds in 1.2 MHz focused ultrasound field [J]. Ultrasonics Sonochemistry, 2006, 13: 480-486.
  • 6C. P. Zhu, S. C. He, M. L. Shan, J. C. Chen, Study of a peak in cavitation activity from HIFU exposures using TA fluorescence [J]. Ultrasonics, 2006, 44(20) : e349-e351.
  • 7CASTELLANOS M M, REYMAN D, SIEIRO C, et al. ESR-spin Trapping Study on the Sonochemistry of Liquids in the Presence of Oxygen: Evidence for the Superoxide Radical Anion Formation[J]. Ultrasonic Sonochemistry, 2001,8(1):17-22.
  • 8VERCET A, LOPEZ P, BURGOS J, et al. Free Radical Production by Manothermosonication[J]. Ultrasonics, 1998,36(2):615-618.
  • 9KUIJPERS M W, KEMMERE M F, KEURENTJES J T, et al. Calorimetric Study of the Energy Efficiency for Ultrasound-induced Radical Formation[J]. Ultrasonics, 2002, 40 (5):675-678.
  • 10P(E)TRIER C, FRANCONY A. Ultrasonic Waste-water Treatment: Incidence of Ultrasonic Frequency on the Rate of Phenol and Carbon Tetrachloride Degradation[J]. Ultrasonics Sonochemistry, 1997,4(4):295-300.

共引文献25

同被引文献31

  • 1吴志敏,韦朝海,吴超飞.H_2O_2湿式氧化处理含酸性红B染料模拟废水的研究[J].环境科学学报,2004,24(5):809-814. 被引量：39
  • 2闫怡新,刘红.低强度超声波强化污水生物处理机制[J].环境科学,2006,27(4):647-650. 被引量：17
  • 3崔福义,左金龙,赵志伟,费霞丽.饮用水中贾第鞭毛虫和隐孢子虫研究进展[J].哈尔滨工业大学学报,2006,38(9):1487-1491. 被引量：23
  • 4冯若,陈兆华,朱昌平,赵逸云,王双维.双频正交辐照的声化学效应研究[J].科学通报,1997,42(9):925-928. 被引量：25
  • 5MCCORMICK N J, PORTER M, WALSH M E. Disinfection by-products in filter backwash water: implications to water quality in recycle designs [ J ]. Water Research, 2010, 44(15): 4581-4589.
  • 6SIVASANKAR T, MOHOLKAR V S. Physical insights into the sonochemical degradation of recalcitrant organic pollutants with cavitation bubble dynamics[ J]. Ultrasonics Sonochemistry, 2009, 16(6) : 769-781.
  • 7GOLASH N, GOGATE P R. Degradation of dichlorvos containing wastewaters using sonochemical reactors : J ]. Ultrasonics Sonochemistry, 2012, 19 (5) : 1051-1060.
  • 8ASHOKKUMAR M, VU T, GRIESER F, et al. Ultrasonic treatment of cryptosporidium oocysts [ J ]. Water Science and Technology, 2003, 47 (3) : 173-177.
  • 9KODA S, MIYAMOTO M, TOMA M, et al. Inactivation of escherichia coli and streptococcus mutans by ultrasound at 500 kHz [ J]. Ultrasonics Sonochemistry, 2009, 16 ( 5 ) : 655-659.
  • 10COLLIS J, MANASSEH R, LIOVIC P, et al. Cavitation microstreaming and stress fields created by microbubbles [J]. Ultrasonics, 2010, 50(2): 273-279.

引证文献2

二级引证文献12

理化检验（化学分册）
2012年 第5期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部