摘要
A novel chiral polyoxometalate（POM）, {[Na（Arg）2]NaH}[AIMo6（OH）6O18].6H2O（1,Arg=L-arginine）has been synthesized by the reaction between Na3[A1Mo6（OH）6O18].8H2O and Arg in aqueous solution and was structu- rally characterized by single-crystal X-ray diffraction, elemental analyses and UV-Vis spectrometry. Compound 1 was an example of Arg based Anderson-type complex. Photocatalytic analysis indicates that compound 1 presents cata- lytic activity for photodegradation of rhodamine-B（RhB） under UV irradiation.
A novel chiral polyoxometalate（POM）, {[Na（Arg）2]NaH}[AIMo6（OH）6O18].6H2O（1,Arg=L-arginine）has been synthesized by the reaction between Na3[A1Mo6（OH）6O18].8H2O and Arg in aqueous solution and was structu- rally characterized by single-crystal X-ray diffraction, elemental analyses and UV-Vis spectrometry. Compound 1 was an example of Arg based Anderson-type complex. Photocatalytic analysis indicates that compound 1 presents cata- lytic activity for photodegradation of rhodamine-B（RhB） under UV irradiation.
基金
Supported by the National Natural Science Foundation of China(Nos.20701005,20701006)
the Science and Technology Development Project Foundation of Jilin Province,China(No.20060420)
the Postdoctoral Station Foundation of Ministry of Education of China(No.20060200002)
the Testing Foundation of Northeast Normal University of China
the Natural Science Foundation of Changchun Normal University of China(No.2010006)
