摘要
A multi-step reaction route was developed to synthesize boron nitride（BN） nanoparticles via the reactionbetween NaN3 and BC13 in a benzene-thermal solution. By means of this route, the crystallinity of BN nanoparticleswas improved via increasing the reaction steps. Meanwhile, a phase transformation from hexagonal BN（hBN） or tur-bostratic BN（tBN） to cubic BN（cBN） occurred, resulting in the increase of cBN content. Moreover, the content ofcBN also slightly increased when the temperature was elevated from 265 ℃ to 280 ℃.
A multi-step reaction route was developed to synthesize boron nitride（BN） nanoparticles via the reactionbetween NaN3 and BC13 in a benzene-thermal solution. By means of this route, the crystallinity of BN nanoparticleswas improved via increasing the reaction steps. Meanwhile, a phase transformation from hexagonal BN（hBN） or tur-bostratic BN（tBN） to cubic BN（cBN） occurred, resulting in the increase of cBN content. Moreover, the content ofcBN also slightly increased when the temperature was elevated from 265 ℃ to 280 ℃.
基金
Supported by the National Natural Science Foundation of China(Nos.21073107,51102151 and 50990061)
the Natural Science Foundation of Shandong Province,China(No.2R2011EMQ002)
the Independent Innovation Foundation(No.2010TS039)
the Postdoctoral Foundation of Shandong University,China
