摘要
A novel mixed-valent heterometallic pentanuclear CoⅢ3 CoⅡ Dy Ⅲ cluster has been rationally assembled taking advantage of a bifunctional ligand with o-vanillin and tripodal tris(hydroxymethyl)aminomethane units. This unique heterometallic cluster represents a rare example of T-shaped molecules exhibiting slow magnetic relaxation.
A novel mixed-valent heterometallic pentanuclear CoⅢ3CoⅡDyⅢ cluster has been rationally assembled taking advantage of a bifunctional ligand with o-vanillin and tripodal tris（hydroxymethyl）aminomethane units. This unique heterometallic cluster represents a rare example of T-shaped molecules exhibiting slow magnetic relaxation.
基金
supported by the National Natural Science Foundation of China (91022009, 20921002)
