期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

Cyanide-bridged W~ⅤMn~Ⅲ single-chain magnet based on an octacoordinate [W(CN)_6(phen)]^- anion 被引量：2

Cyanide-bridged W~ⅤMn~Ⅲ single-chain magnet based on an octacoordinate [W(CN)_6(phen)]^- anion
原文传递
导出
摘要 Reaction of unique [W（CN）6（phen）]- with a magnetically anisotropic Mn Schiff base yielded a wv（5d）-Mnm（3d） bimetallic compound with a linear chain structure. The magnetic properties of the chain complex feature a ferrimagnetic behavior as well as slow magnetic relaxation typical for a single-chain magnet. Reaction of unique [W(CN)6(phen)]- with a magnetically anisotropic Mn Schiff base yielded a WⅤ(5d)-MnⅢ(3d) bimetallic compound with a linear chain structure. The magnetic properties of the chain complex feature a ferrimagnetic behavior as well as slow magnetic relaxation typical for a single-chain magnet.
作者 LEE JinWuk LIM KwangSoo YOON JungHee RYU DaeWon KOO BongHo KOH EuiKwan HONG ChangSeop
机构地区 Department of Chemistry Nano-Bio System Research Team
出处 《Science China Chemistry》 SCIE EI CAS 2012年第6期1012-1017,共6页 中国科学（化学英文版）
基金 supported by the National Research Foundation of Korea Funded by the Korean Government (2011-0003264) by the Priority Research Centers Program through the National Research Foundation of Korea (NRF) Funded by the Ministry of Education, Science and Technology (NRF20110018396)
关键词 tungsten MANGANESE CYANIDE crystal structure single-chain magnet phen 单链 磁体 CN 负离子 Schiff碱 氰桥 双金属化合物
分类号 O611.3 [理学—无机化学]
  • 相关文献

参考文献39

  • 1Coulon C, Miyasaka H, Clerac R. The chemistry and physics of single-molecule magnets. Struct Bonding, 2006, 122: 163-173.
  • 2Miyadaka H, Julve M, Yamashita M, Clerac R. Slow dynamics of the magnetization in one-dimensional coordination polymers: Single-chain magnets. Inorg Chem, 2009, 48: 3420-3437.
  • 3Bogani L, Vindigni A, Sessoli R, Gatteschi D. Single chain magnets: Where to from here? J Mater Chem, 2008, 18: 4750-4758.
  • 4Bai YL, Tao J, Wernsdorfer W, Sato O, Huang RB, Zheng LS. Coexistence of magnetization relaxation and dielectric relaxation in a single-chain magnet. JAm Chem Soc, 2006, 128:16428-16429.
  • 5Sun HL, Wang ZM, Gao S. Strategies towards single-chain magnets. Coord Chem Rev, 2010, 254:1081-1100.
  • 6Coulon C, Clerac R, Wernsdorfer W, Colin T, Miyasaka H. Realization of a magnet using an antiferromagnetic phase of single-chain magnets. Phys Rev Lett, 2009, 102: 167204-167207.
  • 7Miyasaka H, Takayama K, Saitoh A, Furukawa S, Yamashita M, Clerac R. Three-dimensional antiferromagnetic order of single-chain magnets:A new approach to design molecule-based magnets. Chem Eur J, 2010, 16:3656-3662.
  • 8Lescouezec R, Toma LM, Vaissermann J, Verdaguer M, Delgado FS, Ruiz-Perez C, Lloret F, Julve M. Design of single chain magnets through cyanide-bearing six-coordinate complexes. Coord Chem Rev, 2005, 249: 2691-2729.
  • 9Zhang D, Wang H, Chen Y, Ni ZH, Tian L, Jiang J. Hydrogen-bond directed cyanide-bridged molecular mag- nets derived from polycyanidemetalates and Schiff base manganese(Ⅲ) compounds: Synthesis, structures, and magnetic properties. lnorg Chem, 2009, 48: 11215-11225.
  • 10Wang S, Zuo JL. Gao S.Song Y, Zhou HC, Zhang YZ, You XZ. The observation of superparamagnetic behavior in molecular nanowires. J Am Chem Soc, 2004, 126: 8900-8901.

同被引文献7

引证文献2

二级引证文献2

Science China Chemistry
2012年 第6期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部