摘要
Four amine functionalized mesoporous catalysts were synthesized by grafting primary, dualistic and two secondary amines onto the channel walls of mesoporous silica, MCM-41. We examined the effects of organoamine loading amount on the acid-base synergism of the catalysts in the self-condensation reaction of n-butanal, a Knoevenagel condensation and a Henry reaction. We observed the balance of the amine and residual silanol amounts is crucial to the catalytic performances of the functionalized mesoporous catalysts. An optimum organoamine loading amount exists, which is dependent on the organoamine type. There is little difference in the optimum organoamine loading amount between different reactions. The secondary organoamine functionalized MCM-41 exhibits the best catalytic performance in the experimental range.
Four amine functionalized mesoporous catalysts were synthesized by grafting primary, dualistic and two secondary amines onto the channel walls of mesoporous silica, MCM-41. We examined the effects of organoamine loading amount on the ac- id-base synergism of the catalysts in the self-condensation reaction of n-butanal, a Knoevenagel condensation and a Henry re- action. We observed the balance of the amine and residual silanol amounts is crucial to the catalytic performances of the func- tionalized mesoporous catalysts. An optimum organoamine loading amount exists, which is dependent on the organoamine type. There is little difference in the optimum organoamine loading amount between different reactions. The secondary or- ganoamine functionalized MCM-41 exhibits the best catalytic performance in the experimental range.
基金
supported by the National Natural Science Foundation of China (20906062)
Shanghai Municipal Natural Science Foundation(09ZR1423300)
