噻菌灵-锰(Ⅱ)配合物的合成、单晶结构解析及表征

Synthesis,single crystal structure analysis and characterization of thiabendazole-manganese(Ⅱ) complexes

溶剂热法合成了一个新的Mn配合物,[Mn(TBDZ)2]NO3.Cl.H2O(TBDZ=噻菌灵).此配合物属于单斜晶系,P2(1)/c空间群,a=16.003(7),b=11.158(5),c=13.905(6),α=90.00°,β=113.196(5)°,γ=90.00°,V=2282.3(16)3,Z=4.每个锰离子分别与来自两个噻菌灵分子上的两个氮原子形成双螯合结构,同时还与另一个氯离子,一个配位水的氧原子配位,形成了一个变形的八面体结构.未配位的硝酸根离子与配位水,噻菌灵上的另一个亚胺基上的氢原子形成氢键,参与了配合物的空间连接.

： By the way of solvent synthesis, a new Mn polymer was prepared, [Mn（TBDZ）z] NO3·Cl. H2O[TBDZ= thiabendazole]. This polymer belongs to monoclinic and its group space is P2 （1）/c, a = 16. 003（7）A, b =11.158（5）.A c =13.905（6）A, a =90.00°, 8=113.196（5）°, γ=90.00°, V=2282.3（16）Aa, Z =4. Each Manganese ion build double chelate structures with two Nitrogen atoms from thiabendazole, it also coordinated with a chloride ion and an oxygen atom from water. Which help Mn ion to build a deformation of the octahedral tructure. The uncoordinated nitrate ion joined the connection of polymer space by building two hydrogen bonds with a hydrogen from water and a hydrogen from imino which lies on thiaben-dazole.