6种可降解地膜光解模型的研究初探(英文)

Photolytic Model of Six Degradable Mulch Plastic Films

[目的]为了解决新疆地膜污染问题,为可降解地膜的降解机理研究提供可靠的理论依据。[方法]采用室内模拟的方法,研究可降解地膜的降解程度和光照时间的关系,并且经过回归分析拟合出符合其降解规律的降解模型。[结果]试验结果表明:不同类型的可降解地膜的失重率与光照有很大的关系。降解过程未发现杂物,质量却减轻,说明降解产生了气体,证明了紫外线对地膜具有破坏作用。不同的地膜在降解过程中速率有着明显的差异;在相同条件下,诱导期为30d的S4#降解最快,随着紫光光照时间的延长,其降解程度为逐步累积降解的过程。[结论]6种可降解地膜在紫外线照射下失重率和光照天数可以基本上看作是正相关的关系,通过显著性检验后找到数据拟合曲线的降解模型可用逻辑斯蒂模型来进行描述,即Y=a/(1+b×e-ct),并且都达到了显著水平(P<0.01)。

[Objective] This study aimed to solve the mulch plastic film pollution problems in Xinjiang, in order to provide reliable theoretical basis for the research on the degradation mechanism of biodegradable plastic films. [Method] The effect of illumination intensity on the decomposition of decomposable mulching films was investigated through simulating the field condition in laboratory. Regression analysis was employed to fit the processes of film decompositions. [Result] The weight loss ratios of different types of plastic films were closely related with the illumination. There was no sundry produced during the degradation process, but the weight was reduced, indicating that degradation produced gas, thus, ultraviolet rays had destructive effect on mulch plastic films. Different types of plastic films showed significant differences in the degradation speeds, and under the same conditions, the degradation speed of S4# with the induction period of 30 d was the fastest. With the extension of uv illumination time, the degradation became cumulative degradation process. [Conclusion] Under the uv rays, the weight loss ratio and illumination hours is regarded as a positive correlation relationship. The significant inspection shows that the data fitted degradation model can be described by the logistic model of Y = a/（1＋b×e -ct）, and all the parameters show significant differences （P0.01）.