摘要
利用热天平考察了神华和胜利两种典型中国煤直接液化残渣及其萃取产物的失重曲线。实验表明,神华残渣和胜利残渣的轻质组分含量相近,其失重率也相近,但轻质组分组成不同使得失重过程并不一致。升温速率增加,热解最大失重速率增加,最大失重速率温度升高。以残渣各组分失重曲线拟合得到的残渣失重曲线可近似表示残渣的失重曲线。动力学分析表明,由实验数据拟合的活化能和指前因子计算得到的失重曲线,与实际实验得到的失重曲线较为一致。液化残渣在低温区失重率很高,而且这部分失重产物可以通过溶剂萃取的方式得到。
Pyrolysis of two typical Chinese coal liquefaction residues ( Shenhua and Shengli) and their solvent extracts was carded out by TG. The results show that Shenhua and Shengli residue contain similar content of light component, and their weight losses in TGA are similar. However, the different composition of light component in the two residues leads to their difference in TG curves. As increasing of heating rate, the maximum weight loss rate and its corresponding temperature increase. The calculated weight loss calculated from the constitutes is approximately the actual value of the residue. From the kinetic analysis, it is found that the weight loss calculated by the experimental E and k0 agree well with that obtained from the experiment. The weight loss is mainly caused by evaporation of volatile matter which can be extracted by solvent
出处
《燃料化学学报》
EI
CAS
CSCD
北大核心
2012年第6期655-659,共5页
Journal of Fuel Chemistry and Technology
关键词
煤直接液化
残渣
热重
萃取
活化能
指前因子
coal direct liquefaction
residue
thermogravimetric analysis
extract
activation energy
frequency factor