摘要
A series of novel Schiff bases bearing triazole structure were synthesized and characterized by LR and NMR. Mn(OAc)2/Schiff base efficiently catalyzed Henry reaction of nitroalkanes with aldehydes to produce the corresponding products of ^-nitroalcohols, under mild conditions with high yields (up to 99%). A reaction mechanism is proposed based on the experimental results.
A series of novel Schiff bases bearing triazole structure were synthesized and characterized by LR and NMR. Mn(OAc)2/Schiff base efficiently catalyzed Henry reaction of nitroalkanes with aldehydes to produce the corresponding products of ^-nitroalcohols, under mild conditions with high yields (up to 99%). A reaction mechanism is proposed based on the experimental results.
基金
support from the National Natural Science Foundation of China(Nos.20962018, 20862015 and 20562011)