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Ca_4GdO(BO_3)_3:Eu^(3+),Sm^(3+)的发光及离子间的能量转移 被引量:9

Luminescence and Energy Transfer Between Ions in Ca _4GdO(BO_3)_3:Eu^(3+) ,Sm^(3+)
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摘要 Polycrystalline powders of title compound were prepared by solid state reaction at lower temperature. The exitation and emmission spectra of the system were recorded and discussed. The results showed that there occurs an energy transfer from Gd 3+ to Eu 3+ . The luminescence intensity of Eu 3+ was found increased with increasing of Gd 3+ concentration. However, Sm 3+ had a quenching influence on the luminescence of Eu 3+ . Polycrystalline powders of title compound were prepared by solid state reaction at lower temperature. The exitation and emmission spectra of the system were recorded and discussed. The results showed that there occurs an energy transfer from Gd 3+ to Eu 3+ . The luminescence intensity of Eu 3+ was found increased with increasing of Gd 3+ concentration. However, Sm 3+ had a quenching influence on the luminescence of Eu 3+ .
出处 《应用化学》 CAS CSCD 北大核心 2000年第2期183-185,共3页 Chinese Journal of Applied Chemistry
基金 国家自然科学基金资助项目! ( 2 98712 0 9)
关键词 Ca4GdO(BO3)3 发光 能量传递 稀土三硼酸盐 Ca_4GdO(BO_3)_3:Eu^(3+),Sm^(3+) ,luminescence,energy transfer
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