龙脑烯基环己醇型檀香化合物的合成研究

Study on the synthesis of campholenyl cyclohexanol type sandalwood compounds

由龙脑烯醛、哌啶、甲基乙烯基酮、PTSH催化剂等原料，经烯胺中间体、Michael加成、分子内环化、硼氢化钠还原等反应，合成出了具有珍贵檀香气的龙脑烯基环已醇型化合物。对合成条件及反应历程作了探讨，对产物的结构及香气作了鉴定。

Campholenyl cyclohexanol type compounds,having precious sandalwoods-like aroma, were prepared from camphorenal, piperidine, MVK, PTSH catalyst, etc.via intermediate of enamine,additive reaction of Michael,cyclization in the molecule,and reduction by sodium borohydride.The reaction conditions and mechanisms were discussed,the product structures and odor were identified also.