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C_(60)接枝聚(N-乙烯基咔唑)的合成、表征及光电导性能 被引量:7

Preparation, Characterization and Photoconductivity of C_(60) Grafted Poly(N-vinyl carbazole)
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摘要 The C60 grafted poly(N-vinyl carbazole) (PVK) polymer(CGP) was prepared by simple radical polymerization initiated by BPO at 90℃.The products were characterized by UV-Vis, FTIR, GPC and fluorescence and it was proven that C60 was grafted covalently to the PVK. The C60 moiety in the product was about 1. 2% (mass fraction). The photoconductlvity study revealed that the photoconductivity of PVK was improved obviously through grafting C60.The half time of light decaying (t1/2) of CGP reached 0. 35 s. The C60 grafted poly(N-vinyl carbazole) (PVK) polymer(CGP) was prepared by simple radical polymerization initiated by BPO at 90℃.The products were characterized by UV-Vis, FTIR, GPC and fluorescence and it was proven that C60 was grafted covalently to the PVK. The C60 moiety in the product was about 1. 2% (mass fraction). The photoconductlvity study revealed that the photoconductivity of PVK was improved obviously through grafting C60.The half time of light decaying (t1/2) of CGP reached 0. 35 s.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2000年第5期816-818,共3页 Chemical Journal of Chinese Universities
基金 国家自然科学基金 青年基金!(批准号:59703004)
关键词 C60接枝聚(N-乙烯基咔唑) 光电导性能 合成 碳60 Poly(N-vinyl carbazole) (PVK) C_(60) C_(60) grafted PVK Photoconductivity
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