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Mesoporous CeO_2 nanowires as recycled photocatalysts 被引量:5

Mesoporous CeO_2 nanowires as recycled photocatalysts
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摘要 Mesoporous CeO2 nanowires(NWs) were synthesized through a facile hydrothermal process by using triblock copolymer F127 as the template.XRD analysis confirmed the cubic phase of the synthesized CeO2 NWs.High-yield one-dimensional NWs with accessible mesopores could be observed from SEM and TEM images,and the surface area of the material was confirmed to be 273 m2 g-1 with pore width distribution of 6.9-13.8 nm.The mesoporous CeO2 NWs could be used as efficient photocatalysts for organic dye degradation under UV light irradiation,which was superior compared with commercial photocatalyst P-25 and commercial CeO2 powders.The NW structure facilitates the recovery of catalyst by sedimentation,leading to the impressive reusability of these mesoporous CeO2 NWs. Mesoporous CeO2 nanowires (NWs) were synthesized through a facile hydrothermal process by using triblock copolymer F127 as the template. XRD analysis confirmed the cubic phase of the synthesized CeO2 NWs. High-yield one-dimensional NWs with accessible mesopores could be observed from SEM and TEM images, and the surface area of the material was confirmed to be 273 m2 g-1 with pore width distribution of 6.9-13.8 nm. The mesoporous CeO2 NWs could be used as efficient photocatalysts for organic dye degradation under UV light irradiation, which was superior compared with commercial photocatalyst P-25 and commercial CeO2 powders. The NW structure facilitates the recovery of catalyst by sedimentation, leading to the impressive reusability of these mesoporous CeO2 NWs.
作者 SHAO Yue MA Yong
机构地区 College of Chemistry
出处 《Science China Chemistry》 SCIE EI CAS 2012年第7期1303-1307,共5页 中国科学(化学英文版)
基金 supported by the Engineering and Technology Research Center of Food Preservation,Processing and Safety Control of Liaoning Province,Food Safety Key Lab of Liaoning Province (LNSAKF2011027) Key Laboratory Project of Department of Education of LiaoningProvince (2009s004)
关键词 再生催化剂 纳米线 氧化铈 介孔 X射线衍射分析 模板合成 嵌段共聚物 TEM观察 mesopore, CeO2 NWs, photocatalysis, recycle
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  • 1Zhong LS, Hu JS, Cao AM, Liu Q, Song WG, Wan LJ. 3D flowerlike ceria micro/nanocomposite structure and its application for water treatment and CO removal. Chem Mater, 2007, 19:1648-1655.
  • 2Barth S, Hernandez-Ramirez F, Holmes JD, Romano-Rodriguez A. Synthesis and applications of one-dimensional semiconductors. Prog Mater Sci, 2010, 55:563-627.
  • 3Yu T, Joo J, Park Y, Hyeon T. Large-scale nonhydrolytic sol-gel synthesis of uniform-sized ceria nanocrystals with spherical, wire, and tadpole shapes. Angew Chem Int Ed, 2005, 44:7411-7414.
  • 4Yada M, Sakai S, Torikai T, Watari T, Furuta S, Katsuki H. Cerium compound nanowires and nanorings templated by mixed organic molecules. Adv Mater, 2004, 16:1222-1226.
  • 5Sun Z, Zhang H, An G, Yang G, Liu Z. Supercritical CO2-facilitating large-scale synthesis of CeO2 nanowires and their application for solvent-free selective hydrogenation of nitroarenes. J Mater Chem, 2010, 20:1947-1952.
  • 6Lu X, Zheng D, Gan J, Liu Z, Liang C, Liu P, Tong Y. Porous CeO2 nanowires/nanowire arrays: Electrochemical synthesis and application in water treatment. J Mater Chem, 2010, 20:7118-7122.
  • 7Bamwenda GR, Arakawa HJ. Cerium dioxide as a photocatalyst for water decomposition to O2 in the presence of Ceaq^4+ and Feaq^3+ species. Mol Catal A: Chem, 2000, 161:105-113.
  • 8Hernandez-Alonso MD, Hungria AB, Martinez-Arias A, Fernandez- Garcia M, Coronado JM, Conesa JC, Soria J. EPR study of the photoassisted formation of radicals on CeO2 nanoparticles employed for toluene photooxidation. Appl Catal B: Environ, 2004, 50: 167- 175.
  • 9Borker P, Salker AV. Solar assisted photocatalytic degradation of naphthol blue black dye using Ce1-xMnxO2. Mater Chem Phys, 2007, 103:366-370.
  • 10Zhu HY, Lan Y, Gao XP, Ringer SP, Zheng ZF, Song DY, Zhao JC. Phase transition between nanosttuctures of titanate and titanium dioxides via simple wet-chemical reactions. J Am Chem Soc, 2005, 127: 6730-6736.

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