氮杂富勒烯的合成及反应研究进展

Progress in the Synthesis and Reaction of Azafullerene

氮杂富勒烯是富勒烯家族中一类非常重要的化合物,由于其独特的结构和反应活性,近年来引起了人们的广泛关注.因此,对氮杂富勒烯的合成、反应方面的研究进行了概括和总结.氮杂富勒烯的合成主要有3种方法(Wudl,Hirsch,Gan),氮杂富勒烯的反应主要包括自由基反应和亲电芳环取代反应.

Azafullerene is a very important compound in fullerene family,which has been attracted extensive attention re-cently because of its unique structure and reactive activities.Recent progress in the preparation and reaction of azafullerene is summarized in this paper.There are three main methods for the synthesis of azafullerene（Wudl＇s method,Hirsch＇s method and Gan＇s method）.Azafullerene reactions include free radical reactions and electrophilic aromatic substitution reaction.