期刊文献+

聚脲润滑脂稠化剂结构与其性能的关系 被引量:15

The Relationships of Thickener Structures and Properties of Polyurea Grease
下载PDF
导出
摘要 以脂肪胺、芳香胺、脂环胺的不同组合和异氰酸酯为稠化剂,在不同的工艺条件下制备一系列的聚脲润滑脂;利用扫描电子显微镜(SEM)对润滑脂皂纤维微观结构进行表征;探讨不同的稠化剂组成、不同制备工艺对聚脲润滑脂的微观结构和性能的影响。结果表明:单纯均匀颗粒状稠化剂比纤维与颗粒状复合的稠化剂所制备的聚脲脂具有更优的性能;纤维结构以单根形式存在为主的聚脲润滑脂性能优于纤维结构为多根纤维聚集为一股,各股之间交织的聚脲润滑脂。 Using aliphatic amines, aromatic amines and alicyclic amines in different combinations and isocyanate as thickeners, a series of polyurea greases were prepared with different process conditions. The soap fiber microstructure of the grease was characterized by using scanning electron microscopy(SEM). The effects of different thickener composition and the preparation process on microstructure and properties of the polyurea grease were researched. The results show that poly- urea grease with simple uniformly granular thickeners has better performance than that with fiber and particulate composite thickeners. Polyurea grease with fibrous structure mainly in the form of single fiber is superior to that with fiber structure in the form of the aggregated bunch of fibers interwoven between each other.
出处 《润滑与密封》 CAS CSCD 北大核心 2012年第7期5-9,共5页 Lubrication Engineering
基金 国家重点基础研究发展计划(973计划)资助项目(2011CB706603)
关键词 聚脲润滑脂 稠化剂 制备工艺 结构和性能 polyurea grease thickeners preparation process structures and properties
  • 相关文献

参考文献10

  • 1邓才超,郭小川,蒋卓君.脲基润滑脂性能的影响因素[J].合成润滑材料,2006,33(4):31-33. 被引量:7
  • 2杨海宁,姚立丹.2009年中国及全球润滑脂生产分析[C]//全国第十四届润滑脂技术交流会议论文集.石油炼制技术编辑部,2010:4-11.
  • 3Mark W B. High viscosity index PAO with polyurea thickeners in grease compositions: US, 200902747441A1 [ P]. 2009 - 10 -01.
  • 4Washo M. Frictional characteristics of greased rolling contact bearings [ J ]. NLGI Pokesman, 1994,57 ( 11 ) :456 - 462.
  • 5Okamura S,Tyota M. Long life urea grease for high temperature and high speed application [ J ]. NLGI Spokesman, 1992,56 (3) :94 - 100.
  • 6Delgado M A, Sa'nchez M C, Valencia C, et al. Relationship among microstructure rheology and processing of a lithium lubri- cating grease[ J]. Chemical Engineering Research and Design, 2005,83 ( A9 ) : 1085 - 1092.
  • 7Delgado M A, Valencia C, Sa'nchez M C, et al. Influence of soap concentration and oil viscosity on the rheology and micro- structure of lubricating greases [ J ]. Ind Eng Chem Res, 2006, 45:1902 - 1910.
  • 8Moreno G, Valencia C, Franco J M, et al. Influence of molecular weight and free NCO content on the rheologicalproperties of lithium lubricating greases modified with NCO - terminated pre- polymers[ J ]. European Polymer Journal, 2008 ( 44 ) : 2262 - 2274.
  • 9杨玮,姚立丹,郑善伟.脲基润滑脂的结构及反应机理的研究[J].石油学报(石油加工),2000,16(4):38-42. 被引量:26
  • 10姚立丹,郭丽阳,郑善伟,等.稠化剂组分和炼制温度对脲基润滑脂结构和性能的影响[C]//全国第十一届润滑脂技术交流会议论文集.石油炼制技术编辑部,2001:67-70.

二级参考文献5

共引文献31

同被引文献198

引证文献15

二级引证文献38

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部