POMSS配位化合物

Synthesis and Application of POMSS

近20年来,聚倍半硅氧烷金属配合物(POMSS)的合成、物理和化学性质以及应用,取得了飞跃式的发展,是当前的研究热点之一。其所包含的配位元素的种类几乎遍布整个元素周期表,并被广泛地应用于催化剂领域和其他功能材料领域。本文根据配位元素的特点对POMSS配合物进行了分类,并对其合成方法、发展及应用情况做了简单总结,最后对POMSS未来的研究前景进行了展望。

The synthesis strategies, physical and chemical properties, as well as applications of polyhedral oligometallasilsesquioxanes（POMSS） have taken a remarkable leap in recent 20 years. It is still one of the research focuses at present. A rich chemistry of POMSS has developed with elements throughout the periodic table, that used widely as catalysts or silica-supported catalyst models and some other functional materials. In this paper, the developments and applications of POMSS are summarized and reviewed, especially for the status quo of incompletely condensed polyhedral oligomeric silsesquioxanes coordination chemistry.