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微量硼对微量硫引起的纯铁高温脆性断裂的影响

Effect of Trace Boron on High Temperature Brittle Fracture of Iron Caused by Trace Sulfur
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摘要 硫引起的高温脆性断裂是制约钢铁材料生产和使用的核心问题之一,针对此问题,利用高温拉伸试验和SEM断口观察研究了微量硼对含微量硫(质量分数为0.006%)的纯铁高温塑性及断裂方式的影响,在利用扫描俄歇电子谱仪对界面偏析定量分析的基础上,讨论了微量硼影响的原因.结果表明,微量硼的添加能明显提高含微量硫的纯铁的高温塑性,抑制硫界面偏析造成的高温脆性断裂.微量硼的这种影响是由于硼沿界面偏析,显著降低硫的界面偏析倾向,抑制硫界面偏析引起的高温沿晶孔洞形成. The high temperature brittle fracture caused by sulfur is one of key problems to restrict the production and the use of steel. Aiming at this problem, the effect of trace boron on the ductility and fracture mode of iron containing trace sulfur (mass fraction 0.006%) at high temperatures was investigated by tensile tests at high temperatures and SEM observations of fractured surfaces. The role of trace boron was discussed based on analysis of the segregation at interfaces by scanning Auger electron spectroscopy. The experimental results showed that the addition of trace boron increases markedly the high temperature ductility of iron containing trace sulfur and restrains the brittle fracture caused by the interface segregation of sulfur. Such effect of trace boron results from that trace boron can segregate to interfaces of iron, remarkably decreasing the segregation of sulfur and therefore restraining the formation of cavities at grain boundaries caused by intergranular segregation of sulfur.
出处 《东北大学学报(自然科学版)》 EI CAS CSCD 北大核心 2012年第7期958-961,共4页 Journal of Northeastern University(Natural Science)
基金 辽宁省教育厅重点实验室项目(2009S040)
关键词 钢铁 孔洞 高温脆性断裂 iron and steel boron sulfur cavity high temperature brittle fracture
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  • 1周建安,朱苗勇,潘时松.PFG型铁液预处理喷粉罐的研制及应用[J].中国冶金,2006,16(11):27-29. 被引量:5
  • 2Baniya S, Hino M, Kaji T, et al. Sulphur solubility in CaO- Al2O3 and CaO-Al2O3-CaF2 slags [J]. Developments in Chemical Engineering & Mineral, 2006, 14 ( 3/4 ) : 171 - 175.
  • 3Eriksson G, Pelton A D. Critical evaluation and optimization of the themodynamics properties and phase diagrams of the CaO-Al2O3, Al2O3-SiO2, and CaO-Al2O3-SiO2 systems [ J ]. Metall Trans, 1993,24B(10) :807 - 816.
  • 4Inoue R, Inoue H, Suito H. Partitions of nitrogen and sulphur between CaO-Al2O3 melts and liquid iron [J]. ISIJ International, 1991,31(12):1389-1395.
  • 5Presem V, Korousic B, Hastie J W. Thermodynamic conditions for inclusions modification in calcium freated steel [J]. Steel Research, 1991,62(7):289-295.
  • 6Simeonor S R, Ivancher I N, Hainadjiev A V. Sulphur equilibrium distribution between CaO-CaF2-SiO2-Al2O3 slags and carbon saturated iron[J]. ISIJ International, 1991,31 (12):1396-1399.
  • 7张信昭.喷粉冶金基本原理[M].北京:冶金工业出版社,2004.
  • 8Liu C M,Proc UHPM’94,1994年,500页
  • 9Liu C M,Metall Trans A,1992年,23卷,263页
  • 10S. -H. Chen,T. Takasugi,D. P. Pope. The effects of trace impurities on the ductility of a Cr-Mo-V steel at elevated temperatures[J] 1983,Metallurgical Transactions A(3):571~580

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