期刊文献+

Sn掺杂对Zn_4Sb_3热电输运性能的影响研究

Thermoelectric properties of Sn-doped Zn_4Sb_3 system
下载PDF
导出
摘要 在5-310K温度范围内,研究了Sn替代对化合物(Zn1-xSnx)4Sb3的低温热电性能的影响。研究结果表明相对于无掺杂的Zn4Sb3,(Zn1-xSnx)4Sb3(x≠0)的低温热导率明显降低,并且随着Sn掺杂含量的增加而不断降低。实验结果也发现,掺杂Sn后化合物的直流电阻率和热电势都减小,且随着Sn掺杂量的增加而不断减小。 In this paper, the effects of Sn substitution of Zn on thermoelectric properties of (Zn1-xSnx)4Sb3 were studied at the temperatures from 5K to 310IC The results showed that low-temperature thermal conductivity of the doped β-(Zn1-xSnx)4Sb3 (x≠0) reduced remarkably as compared to that of Zn4Sb3, and decreased monotonously with increasing Sn content x. Meanwhile, DC electrical resistivity and thermopower of the doped compounds became smaller than that of un-doped Zn4Sb3, and decreased monotonously with increasing Sn content x.
作者 刘峰 章其林
机构地区 安徽工程大学
出处 《铜陵学院学报》 2012年第3期98-100,共3页 Journal of Tongling University
基金 安徽省自然科学基金项目(编号1208085QA16) 安徽省高校省级自然科学研究项目(编号:KJ2010B024) 安徽工程大学引进人才启动基金项目(编号:2008YQ006)研究成果
关键词 Zn4Sb3 热电势 热导率 热电性能 Zn4Sb3 Thermopower , Thermal conductivity Thermoelectric properties
  • 相关文献

参考文献11

  • 1G.D.Mahan. Good Thermoelectrics[J].Solid State Physics Advances in Research and Applications,1997,(51):81-157.
  • 2F.J.DiSalvo. Thermoelectric Cooling and Power Generation[J].Science,1999,(285):703-706.
  • 3B.C.Sales,D.Mandrus,R.K.Williams. Filled skutterudite antimonides:A new class of thermoelectric materials[J].Science,1996,(272):1325-1328.
  • 4T.M.Tritt. Recent Trends in Thermoelectric Materials Research I(Semiconductors and Semimetals)[J].San Academic Press Diego,2001,(69):1.
  • 5T.M.Tritt. Holey and unholy semiconductors[J].Science,1999,(283):804-805.
  • 6G.S.Nolas,J.Sharp,H.J.Goldsmid. Thermoelectrics Basic Principles and New Materials Development[M].Berlin Heidelberg:Springer-Verlag,2001.
  • 7H.W.Mayer,I.Mikhail,K.Schubert. (U)ber einige phasen der Mischungen ZnSbN and CdSbN[J].Journal of the Less-Common Metals,1978,(59):43.
  • 8M.Tapiero,S.Tarabichi,J.G.Gies,C.Noguet,J.P.Zielinger,M.Joucla,J.Loison,M.Robino. Preparation and characterization of Zn4Sb4[J].Solar Energy Materials,1985,(12):257.
  • 9T.Caillat,J.P.Fleurial,A.Borshevsky. Preparation and thermoelectric properties of semiconducting Zn4Sb3[J].Journal of Physics and Chemistry of Solids,1997,(58):1119-1125.
  • 10G.Nakamoto,T.Souma,M.Yamaba,M.Kurisu. Thermoelectric properties of(Zn1-xCdx)4Sb3 below room temperature[J].Journal of Alloys and Compounds,2004,(377):59-65.

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部