摘要
以3,4,9,10-苝四酸二酐为原料,设计并合成了三个新型的苝酰亚胺衍生物———N,N'-二(1-戊基己基)-3,4,9,10-苝四羧酸二酰亚胺,N,N'-二(1-戊基己基)-1,6,7,12-四(对叔丁基苯氧基)-3,4,9,10-苝四羧酸二酰亚胺和N,N'-二(4-六氟异丙醇基苯基)-1,6,7,12-四(对叔丁基苯氧基)-3,4,9,10-苝四羧酸二酰亚胺,其结构经1H NMR和MS表征。用UV-Vis和荧光光谱研究了他们的光学性质。
Three novel perylene diimide derivatives,N,N′-di(1-pentylhexyl)-
perylene-3,4,9,10-tertracarboxylic acid diimide,N,N′-di(1-
pentylhexyl)-1,6,7,12-tetra(4-t-butylphenoxy)-perylene-3,4,9,10-
tertracarboxylic acid diimide and N,N′-di(4-hexafluoroisopropanol
phenyl)-1,6,7,12-tetra(4-t-butylphenoxy)-perylene-3,4,9,10-
tertracarboxylic acid diimide,were synthesized from 3,4,9,10-
perylenetetracarboxylic dianhydride.The structures were characterized
by 1H NMR and MS.The optical properties of them were investigated by
UV-Vis and fluorescence spectrum.
出处
《合成化学》
CAS
CSCD
北大核心
2012年第4期421-424,429,共5页
Chinese Journal of Synthetic Chemistry
基金
国家重点基础研究发展计划(973)资助项目(2011CB706902)
关键词
苝四酸二酐
苝酰亚胺
合成
光学性质
perylenetetracarboxylie dianhydride
perylene diimide
synthesis
optical property