新型苝酰亚胺衍生物的合成及其光学性能

Synthesis and Optical Properties of Novel Perylene Diimide Derivatives

以3,4,9,10-苝四酸二酐为原料,设计并合成了三个新型的苝酰亚胺衍生物———N,N'-二(1-戊基己基)-3,4,9,10-苝四羧酸二酰亚胺,N,N'-二(1-戊基己基)-1,6,7,12-四(对叔丁基苯氧基)-3,4,9,10-苝四羧酸二酰亚胺和N,N'-二(4-六氟异丙醇基苯基)-1,6,7,12-四(对叔丁基苯氧基)-3,4,9,10-苝四羧酸二酰亚胺,其结构经1H NMR和MS表征。用UV-Vis和荧光光谱研究了他们的光学性质。

Three novel perylene diimide derivatives,N,N′-di（1-pentylhexyl）- perylene-3,4,9,10-tertracarboxylic acid diimide,N,N′-di（1- pentylhexyl）-1,6,7,12-tetra（4-t-butylphenoxy）-perylene-3,4,9,10- tertracarboxylic acid diimide and N,N′-di（4-hexafluoroisopropanol phenyl）-1,6,7,12-tetra（4-t-butylphenoxy）-perylene-3,4,9,10- tertracarboxylic acid diimide,were synthesized from 3,4,9,10- perylenetetracarboxylic dianhydride.The structures were characterized by 1H NMR and MS.The optical properties of them were investigated by UV-Vis and fluorescence spectrum.