四官能度过氧化物JWEB50引发的PS-b-PMMA合成与表征

Synthesis and characterization of block copolymer PS-b-PMMA with tetrafunctional initiator JWEB50

引言 嵌段共聚物是具有两种或两种以上不同链段的聚合物,不同链段间存在的化学键限制了聚合物的相分离程度,易形成微相分离结构,而嵌段共聚物能作为聚合物共混体系的相容剂,只需加入少量（1％～5％），就能大大提高两种均聚物之间的相容性。

With the aim of synthesis block copolymers by traditional free radical polymerization,a diblock copolymer,polystyrene-b-poly（methyl methacrylate）（PS-b-PMMA）,was prepared by free radical polymerization with a tetra-functional peroxide initiator JWEB50.The unique feature of this initiator is the fact that one initiator contains four peroxide groups which can be sequential decomposited.The polymerization of the formation of the block copolymer was carried out by two stages.First,the polymerization of styrene（St）using JWEB50 was investigated and the polystyrene with peroxide（PSI）was obtained,which was used in the second stage to initiate the second monomer,methyl methacrylate（MMA）.Selective solvent extraction was used for separation of the block polymer from the homopolymers.The separation technique was found to be efficient by gel permeation chromatography（GPC）.The block copolymer was characterized by gel permeation chromatography（GPC）,1H-nuclear magnetic resonance（1H NMR）,Fourier transform infrared spectrometer（FTIR）.The results showed that the polystyrene-b-poly（methyl methacrylate）could be synthesised with JWEB50.The transmission electron microscope（TEM）analysis showed that the polymer could be used as the compatilizer to improve the compatibility of PS/PMMA blends.