期刊文献+

钒氧配合物的合成及其催化乙烯聚合反应性能研究 被引量:1

SYNTHESIS OF OXO-VANADIUM COMPLEX AND ITS CATALYTIC PERFORMANCE IN ETHYLENE POLYMERIZATION
下载PDF
导出
摘要 采用二(2-乙基己基)磷酸、2-乙基己基磷酸-2-乙基己基酯、磷酸三丁酯及正辛醇4种萃取剂,通过萃取法合成了4种钒氧配合物。钒氧配合物的结构用元素分析仪及红外光谱(IR)仪表征,聚合产物结构用凝胶渗透色谱仪(GPC)、差热(DSC)及核磁共振波谱(13C NMR)仪测定。结果表明,合成的钒氧配合物在Et3Al2Cl3的活化下,常压下催化乙烯聚合反应的活性为23~57 kg/(mol.h),产品为线性高密度聚乙烯,黏均相对分子质量为4 800~9 500,相对分子质量分布为4.5左右,熔点在136~138℃之间。 Four extraction agents,i.e.di-(2-ethylhexyl)-phosphoric acid(P 204),2-ethylhexyl phosphoric acid mono-(2-ethylhexyl) ester(P 507),tributyl phosphate(TBP) and 1-octanol(NOOH),were used to synthesize oxo-vanadium complexes by extraction method,and the synthesized complexes were used as catalysts for ethylene polymerization.These four complexes were characterized by elemental analysis,FT-IR and the structures of the polymerization products were characterized by GPC,DSC and 13 C NMR.Test results showed that under atmospheric pressure,activated by Et 3 Al 2 Cl 3,the catalytic activities for ethylene homopolymerization of these catalysts were in the range of 23—57 kg/(mol.h),and the obtained polymers were linear high density polyethylene,with M ν =(4.8—9.5) × 10 3,PDI =4.5,T m = 136—138 ℃.
出处 《石油炼制与化工》 CAS CSCD 北大核心 2012年第8期44-47,共4页 Petroleum Processing and Petrochemicals
基金 广西教育厅科研项目(200911LX435) 钦州市科学研究与技术开发计划项目(20093203) 钦州学院科研项目(2010XJKY-48C)
关键词 钒氧配合物 萃取 乙烯 聚合 oxo-vanadium complex extraction ethylene polymerization
  • 相关文献

参考文献12

  • 1Hagen H, Boersma J, Van Koten G. Homogeneous vanadium- based catalysts for the Ziegler-Natta polymerization of alpha- olefins[J]. Chem Soc Rev, 2002,31(6) : 357-364.
  • 2王开毅.萃取化学[M].湖南:中南工业大学出版社,1991:34-42.
  • 3陈敏娥,黄贵秋,熊拯,张艳军.VO(P_(204))_2/烷基铝合成低分子量3,4-聚异戊二烯[J].化学试剂,2010,32(4):345-348. 被引量:4
  • 4Cao Lihui, Dong Weimin,Jiang Liansheng, et al. Polymeriza tion of 1,3-butadiene with VO(Pzo4 )z and VO(P07 )zactiva- ted by alkylaluminum[J]. Polymer,2007,48(9) :2475-2480.
  • 5曹丽辉,高巍,万雄,董为民,张学全.用于烯烃均聚和共聚的新型催化剂VO(P_(204) )_2 /Et_3Al_2Cl_3(英文) [J].合成橡胶工业,2005,28(2):147-147. 被引量:1
  • 6Mc Dowell W J,Perdue P T,Case G N. Purification of di(2- ethylhexyl) phosphoric acid[J].J Inorg Chem, 1976,38 : 2127- 2129.
  • 7安家驹,陈之川.无机化合物合成手册【M].北京:化学工业出版社.1986.
  • 8Sato T, Nakamura T. Studies on electronic spectrum and electron spin resonance of vanadium (]V) complexes with organophosphorus compounds and high molecular weight amines[J]. Bull Chem Soc Jpn, 1981,54:3387-3390.
  • 9Tedesco P H,de Rumi V B. Vanadium( V ) extraction by tri- n-butylphosphate from hydrochloric acid solutions[J]. J Inorg Nucl Chem,1980, 42:269-272.
  • 10Schohe T G, Meijerink N L, Schoffeleers H M, et al. Mark- houwink quation and GPC calibration for linear short chain branched polyolefines, including polypropylene and ethylene- propylene eopolymers [J]. Journal of Applied Polymer Science, 1984,29(12) :3763-3782.

二级参考文献21

  • 1李桂连,董为民,姜连升,张学全,王佛松.改性甲基铝氧烷和烷基铝活化的新癸酸钕催化剂催化异戊二烯聚合[J].催化学报,2005,26(10):879-883. 被引量:4
  • 2MARWEDE G W,STOLLFUB B,SUMNER A J M.Current status of tyre elastomers in Europe[J].Kautsch Gummi Kunstst,1993,46(5):380-388.
  • 3NORDSIEK K H,WOLPERS J.High Tg polyisoprenes for superior wet grip of tire treads[J].Kautsch Gummi Kunstst,1990,43(9):755-760.
  • 4BIRYUKOVA I I,VISHNITSKII A S,GOVOROVA O A,et al.Use of 3,4-polyisoprene to improve technological characteristics of rubber mixtures based on ethylene-propylene rubbers[J].Kauch Rezina,1995,6(4):12-15.
  • 5HALASA A F,HSU W L.Synthesis of high vinyl elastomers via mixed organolithium and sodium alkoxide in the presence of polar modifier[J].Polymer,2002,43(25):7 111-7 118.
  • 6NATTA G,PORRI L,CARBONARO A.Polymerization of conjugated diolefins by homogeneous aluminum alkyl-titanium alkoxide catalyst systems.Ⅱ.1,2-polybutadiene and 3,4-polyisoprene[J].Makromol.Chem.,1964,77(1):126-138.
  • 7SWIFT H E,BOZIK J E,WUC Y.Specific catalysis witlI iron coordination complexes[J].J.Catal.,1970,17(3):331-340.
  • 8ISILM F,BISWAS R K.Kinetcs of solvent extraction fo metal ions with HDEHP-Ⅱ:kinetics and mechanism of solvent extraction of V(Ⅳ) from acidic aqueous solutions with bis(2-ethylhexyl) phosphoric acid in benzene[J].J.Inorg.Nucl.Chem.,1980,42(3):421-429.
  • 9SATO H,TANAKA Y.1HNMR study of polyisoprenes[J].J.Polym.Sci.Polym.Chem.Ed.,1979,17(11):3 551-3 558.
  • 10JEAN P K,GILBERT F,BERND K.Determination the microstructure of polyisoprenes by resonance magnetic nuclear and spectroscopic infrared[J].Bull.Soc.Chem.Fr.,1967,12(7):4 759-4 764.

共引文献3

同被引文献9

引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部