摘要
One novel organic-inorganic hybrid materials with 4,4＇-bipy ligands and copper chlorine coordination polymers as linkers,with new topology,{[Cu^I（4,4＇-bipy）]_（10）Cl_2（SiW_（12）O_（40））_2}·6H_2O（1）（4,4＇-bipy = 4,4＇-bipyridine）,has been hydrothermally synthesized. The single crystal X-ray structural analysis reveals that the structure of 1 is constructed from classical Keggin anions and[Cu^I（4,4＇- bipy）]cations into a novel,three-dimensional（3D） polyoxometalates（POMs）based network.From the topological view,compound 1 is a novel（3.4^4.5^2.6^3）（3^2.4^4.5^6.6^9） topology.The electrochemical and photocatalysis properties of 1 have been investigated in details.
One novel organic-inorganic hybrid materials with 4,4＇-bipy ligands and copper chlorine coordination polymers as linkers,with new topology,{[Cu^I（4,4＇-bipy）]_（10）Cl_2（SiW_（12）O_（40））_2}·6H_2O（1）（4,4＇-bipy = 4,4＇-bipyridine）,has been hydrothermally synthesized. The single crystal X-ray structural analysis reveals that the structure of 1 is constructed from classical Keggin anions and[Cu^I（4,4＇- bipy）]cations into a novel,three-dimensional（3D） polyoxometalates（POMs）based network.From the topological view,compound 1 is a novel（3.4^4.5^2.6^3）（3^2.4^4.5^6.6^9） topology.The electrochemical and photocatalysis properties of 1 have been investigated in details.
基金
supported by the Key Project of Chinese Ministry of Education(No.211048)
Program for New Century Excellent Talents in Heilongjiang Provincial University of China(No.1154-NCET-010)
