摘要
Title polymeric complex(EPU Eu(Ⅲ)) was obtained from triisobutoxy euro pium Eu(C 3H 7O) 3 with electropolyurushiol in isobutyl alcohol. The structure and property of the complex were characterized by FT IR, XPS, DMTA, AES, TG DTA and fluorescence spectrophotometry. The complex with Eu(Ⅲ) content reached up to 9 6% was insoluble in most organic solvents. Its electric resistance was 1 25×10 5 MΩ(that of EPU was 7 90×10 4 MΩ). Its T g and thermal resistance was considerably greater than that of EPU.
Title polymeric complex(EPU Eu(Ⅲ)) was obtained from triisobutoxy euro pium Eu(C 3H 7O) 3 with electropolyurushiol in isobutyl alcohol. The structure and property of the complex were characterized by FT IR, XPS, DMTA, AES, TG DTA and fluorescence spectrophotometry. The complex with Eu(Ⅲ) content reached up to 9 6% was insoluble in most organic solvents. Its electric resistance was 1 25×10 5 MΩ(that of EPU was 7 90×10 4 MΩ). Its T g and thermal resistance was considerably greater than that of EPU.
出处
《应用化学》
CAS
CSCD
北大核心
2000年第3期325-327,共3页
Chinese Journal of Applied Chemistry
基金
福建省自然科学基金
关键词
电化学聚合
漆酚
铕
配合物
聚合物
性质
合成
electrochemical polymerization,urushiol,europium,polymeric complex