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电化学聚合漆酚-铕配合物的合成及性质 被引量：5

Synthesis and Property of Polymeric Complex of Electropolyurushiol(EPU) with Europium
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摘要 Title polymeric complex(EPU Eu(Ⅲ)) was obtained from triisobutoxy euro pium Eu(C 3H 7O) 3 with electropolyurushiol in isobutyl alcohol. The structure and property of the complex were characterized by FT IR, XPS, DMTA, AES, TG DTA and fluorescence spectrophotometry. The complex with Eu(Ⅲ) content reached up to 9 6% was insoluble in most organic solvents. Its electric resistance was 1 25×10 5 MΩ(that of EPU was 7 90×10 4 MΩ). Its T g and thermal resistance was considerably greater than that of EPU. Title polymeric complex(EPU Eu(Ⅲ)) was obtained from triisobutoxy euro pium Eu(C 3H 7O) 3 with electropolyurushiol in isobutyl alcohol. The structure and property of the complex were characterized by FT IR, XPS, DMTA, AES, TG DTA and fluorescence spectrophotometry. The complex with Eu(Ⅲ) content reached up to 9 6% was insoluble in most organic solvents. Its electric resistance was 1 25×10 5 MΩ(that of EPU was 7 90×10 4 MΩ). Its T g and thermal resistance was considerably greater than that of EPU.
作者 唐洁渊 高锋 章文贡 王文
机构地区 福建师范大学高分子研究所
出处 《应用化学》 CAS CSCD 北大核心 2000年第3期325-327,共3页 Chinese Journal of Applied Chemistry
基金 福建省自然科学基金
关键词 电化学聚合 漆酚 铕 配合物 聚合物 性质 合成 electrochemical polymerization,urushiol,europium,polymeric complex
分类号 O634.3 [理学—高分子化学] O631.5 [理学—高分子化学]
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参考文献3

  • 1沈国才，硕士学位论文，1998年
  • 2汪联辉，博士学位论文，1997年
  • 3章文贡，福建师范大学学报，1978年，1期，1页

同被引文献21

  • 1朱毅■,赵凤云.邻氨基苯酚的电化学聚合[J].高等学校化学学报,1993,14(12):1668-1670. 被引量：6
  • 2章文贡 甘景镐.－[J].福建师范大学学报,1978,(1):1-1.
  • 3Long D D,Marx K A,Zhou T. Amperometric Hydrogen Peroxide Sensor Electrodes Coated with Electropolymerized Tyrosine Derivative and Phenolic Films[J].J Electroanal Chem,2001 ,SOle 1) :107-113.
  • 4Gozen B, Berrin D D. Anticorrosive Properties of Electrosynthesized Poly ( m-aminophenol) on Copper from Aqueous Phenylphosphonic Acid Solution[J]. Prog Org Coat, 2009 ,64 ( 1 ) : 57 -66.
  • 5Noureddine B T , Andre S. Electrochemical Removal of Phenol in Alkaline Solution: Contribution of Anodic Polymerization on Different Electrode Materials[J]. Elechtrochim Acta, 2009 ,54 : 48094816.
  • 6Hideki K, Y ohsuke N , Mikio K, et al. Electrochemical Oxidation of Bisphenol A: Application to the Removal of Bisphenol A Using a Carbon Fiber Electrode[J]. Chemosphere,2001 ,45(1) :3743.
  • 7Hou H Y , Vacandio F, Di Vona M L, et al. Sulfonated Polyphenyl Ether by Electropolymerization[J]. Electrochim Acta, 2012,81 (1) :58-63.
  • 8Hou H Y,Di Vona M L,Knauth P. Durability of Sulfonated Aromatic Polymer for Proton-exchange-membrane Fuel Cells[J]. Chem Sus Chem,2011,4(1l) :1526-1536.
  • 9Joseph 0, Fethi B, Tebello N. Electro-oxidation of Phenol and Its Derivatives on Poly-Ni( OH) TPhPyPc Modified Vitreous Carbon Electrodes[J].J Electroanal Chem,2005 ,576(1) :323-332.
  • 10Di Vona M L, Sgreccia E, Tamilvanan M, et al. High Ionic Exchange Capacity Polyphenylsulfone ( SPPSU) and Polyethersulfone ( SPES) Cross-linked by Annealing Treatment: Thermal Stability, Hydration Level and Mechanical PropertiesJ J].J Membr Sci,2010,354(l) :134-141.

引证文献5

二级引证文献13

应用化学
2000年 第3期

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