温控相转移催化——水/有机两相催化新进展

Thermoregulated Phase-transfer Catalysis ——Recent Advances in Water/Organic Biphasic Catalysis

综述了“温控相转移催化”的原理 ,温控膦配体的设计、合成及其在水溶性极小的底物高碳烯烃的水 /有机两相氢甲酰化反应中的应用效果 .

Water/organic biphasic catalysis provided a kind effective way for solving the problem of difficulty from recovering the catalyst in homogeneous catalysis theoretically and practically. So far its application range has been seriously restricted by the water solubility of the substrates. Such a restriction will be fundamentally eliminated by thermoregulated phase transfer catalysis. The principle of the thermoregulated phase transfer catalysis, the design and synthesis of thermoregulated phase transfer ligands and their application in the water/organic two phase hydroformylation of higher olefins severally insoluble in water, were systematically introduced.