摘要
考察了SbCl5对杂多酸 (HPA)催化i C4 H10 /C4 H8烷基化反应的修饰作用 ,用Hammett指示剂测定了SbCl5/HPA催化剂的酸强度 .结果表明 ,经SbCl5修饰的HPA的酸强度有所提高 ,SbCl5的加入量、反应温度及反应时间对烷基化油收率及产物分布均有不同的影响 .
The modification effect of SbCl 5 on isobutane alkylation with butene catalyzed by heteropoly acid (HPA) was investigated, the acid strength of SbCl 5/HPA catalyst was determined by the traditional method of Hammett indicators. The results revealed that SbCl 5 enhanced the acid strength of HPA, and that the alkylate yield and the product distribution were influenced under different conditions, such as the added amount of SbCl 5, the reaction temperature and the reaction time.
出处
《催化学报》
CSCD
北大核心
2000年第3期243-246,共4页
基金
国家自然科学基金!"九五"重大资助项目 ( 2 9792 0 76)
关键词
异丁烷
丁烯
烷基化
杂多酸
LEWIS酸
催化剂
isobutane
butene
alkylation
heteropoly acid
acid strength
Lewis acid
antimony pentachloride