9-Benzylidene-9H-fluorene Derivatives Linked to Monoaza- 15-crown-5： Synthesis and Metal Ion Sensing

9-Benzylidene-9H-fluorene Derivatives Linked to Monoaza- 15-crown-5： Synthesis and Metal Ion Sensing

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摘要 Two kinds of novel styryl chemosensory 2-FMNC and 3-FMNC, were designed and synthesized by an apporiate introduction of 9-benzylidene-9H-fluorene group as fluorophore with the aim at avoiding photoisomerisation. These 9-benzylidene-9H-fluorene derivatives showed the similar selectivity and sensitivity upon addition of metal ions. The sensitivity of FMNC to alkaline earth metal ions was Ba2＋〉 Sr2＋〉Ca2＋≈Mg2＋. Two kinds of novel styryl chemosensory 2-FMNC and 3-FMNC, were designed and synthesized by an apporiate introduction of 9-benzylidene-9H-fluorene group as fluorophore with the aim at avoiding photoisomerisation. These 9-benzylidene-9H-fluorene derivatives showed the similar selectivity and sensitivity upon addition of metal ions. The sensitivity of FMNC to alkaline earth metal ions was Ba2＋〉 Sr2＋〉Ca2＋≈Mg2＋.

作者曹靖李阳冯俊香

机构地区 College of Chemistry Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education

出处《Chinese Journal of Chemistry》 SCIE CAS CSCD 2012年第7期1571-1574,共4页 中国化学（英文版）

关键词 15-aza-5-crown ether 9-benzylidene-9H-fluorene alkaline earth metal ion 15-aza-5-crown ether, 9-benzylidene-9H-fluorene, alkaline earth metal ion

分类号 O657.75 [理学—分析化学] TQ241.54 [化学工程—有机化工]

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1McDonagh, C.; Burke, C. S.; MacCraith, B. D. Chem. Rev. 2008, 108,400.
2Wei, W.; Xu, C.; Ren, J.; Xu, B.; Qu, X. Chem. Cornrnun. 2012, 48, 1284.
3Dai, H.; Liu, F.; Gao, Q.; Fu, T.; Kou, X. Luminescence 2011,26, 523.
4Wang, H. H.; Xue, L.; Qian, Y. Y.; Jiang, H. Org. Lett. 2010, 12, 292.
5He, H. R.; Mortellaro, M. A.; Leiner, M. J. P.; Young, S. T.; Fraatz, R. J.; Tusa, J. K. Anal. Chem. 2003, 75,549.
6Addleman, R. S.; Bennett, J.; Tweedy, S. H.; Elshani, S.; Wai, C. M. Talanta 1998, 46, 573.
7Fedorova, O. A.; Fedorov, Y. V.; Labazava, l. E.; Gulakova, E. N.; Saltiel,J. PhotoChem. Photobiol. Sci. 2011, 10, 1954.
8Cazaux, L.; Faher, M.; Lopez, A.; Picard, C.; Tisnes, P. J. PhotoChem. Photobiol. A: Chem. 1994, 77,217.
9Ahmad, A. R.; Mehta, L. K.; Parrick, J. Tetrahedron 1995, 51, 12899.
10Sui, Z.; Hanan, N. J.; Phimphivong, S.; Wysocki, R. Jr.; Saavedra, S. S. Luminescence 2009, 24, 236.

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2WANG Jun,XU Hong,ZHOU Hua,WEI Ping.Crystal Structure and Characterization of 2-N-(2-Hydroxy-benzylidene) Furanmethanoamine Nickel(II) Complex[J].Chinese Journal of Structural Chemistry,2005,24(8):909-912. 被引量：1
3孙振范.4-[(4-{[4-({4-[(4-Amino-benzylidene)-amino]-benzylidene}-amino)-benzylidene]-amino}-benzylidene)-amino]-benzcic　acid的电子结构和非线性光学性质[J].海南师范学院学报,2001,14(3):63-67.
4徐清,熊威,王清琪,李星,干宁.Synthesis, Crystal Structure and Properties of 2,7-Bis[4-(diphenylamino)phenyl]fluorene[J].Chinese Journal of Structural Chemistry,2012,31(10):1423-1428. 被引量：3
5谢楠,陈懿.Design and Synthesis of a Selective Chemosensor for Zn^2＋[J].Chinese Journal of Chemistry,2006,24(12):1800-1803. 被引量：2
6Mao Xiang Wang Xiang Ming Meng Man Zhou Zhu Qing Xiang Guo.A novel selective fluorescent chemosensor for Cu(Ⅱ)[J].Chinese Chemical Letters,2007,18(11):1403-1406.
7Zahed Karimi-Jaberi,Mohammad Reza Nazarifar,Baharak Pooladian.Tris(hydrogensulfato) boron as a solid heterogeneous catalyst for the rapid synthesis of α,α'-benzylidene bis(4-hydroxycoumarin) derivatives[J].Chinese Chemical Letters,2012,23(7):781-784. 被引量：2
8芴衍生物的合成及研究进展[J].医药中间体及其化工原料,2004(4):33-33.
9Fu Yi Zhang,Chun Li Wu,Cui Zhang,Hong Min Liu.Stereoselective synthesis and crystal structure of 4,6-O-benzylidene-N-octyl-D-allosamine hydrochloride[J].Chinese Chemical Letters,2010,21(7):798-801.
10LIAO Yi,SHI Li-li,FENG Ji-kang,YANG Li,REN Ai-min.Luminescent Properties of Mercury-taining Diethynylfluorene Derivatives[J].Chemical Research in Chinese Universities,2007,23(1):92-95.

Chinese Journal of Chemistry

2012年第7期

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9-Benzylidene-9H-fluorene Derivatives Linked to Monoaza- 15-crown-5： Synthesis and Metal Ion Sensing

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