Hydrophosphonylation of Aldimines under Catalysts-Free Conditions

Hydrophosphonylation of Aldimines under Catalysts-Free Conditions

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摘要 Trimethylsilyl phosphite reacted with aldimines efficiently under catalysts-free conditions, giving a-aminophosphonates in good to excellent yields. Furthermore, the reaction can be scaled-up easily and the high yield can be maintained. Trimethylsilyl phosphite reacted with aldimines efficiently under catalysts-free conditions, giving a-aminophosphonates in good to excellent yields. Furthermore, the reaction can be scaled-up easily and the high yield can be maintained.

作者蔡志华范业成杜广芬何林

机构地区 Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan

出处《Chinese Journal of Chemistry》 SCIE CAS CSCD 2012年第7期1658-1662,共5页 中国化学（英文版）

关键词 trimethylsilyl phosphite ALDIMINES a-aminophosphonates catalysts-flee trimethylsilyl phosphite, aldimines, a-aminophosphonates, catalysts-flee

分类号 O623.731 [理学—有机化学] TQ325.14 [化学工程—合成树脂塑料工业]

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Chinese Journal of Chemistry

2012年第7期

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Hydrophosphonylation of Aldimines under Catalysts-Free Conditions

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