Electrolytic Production of NF3 Using Boron-Doped Diamond Anode in Molten NH4F·2HF
Electrolytic Production of NF3 Using Boron-Doped Diamond Anode in Molten NH4F·2HF
关键词
掺硼金刚石
NF3
阳极液
电解法生产
NH4F
金刚石结构
电流效率
BDD
BDD (boron-doped diamond) electrode, electrochemical synthesis of NF3, boron concentration, current efficiency forNF3 formation, degradation of BDD anode.
参考文献5
-
1Glemser, O.; Schroeder, J.; Knaak, J. Notiz Zur Darstellung Von Stickstofftrifluorid Durch Elektrolyse Von Geschmolzene Ammoniumhydrogenfluorid. Chem. Bet. 1966, 99, 371-374.
-
2Tasaka, A. Denkaihou ni Yoru Sanfukkachisso no Gousei ni Kansuru Kenkyu. Study on Synthesis of Nitrogen Trifluoride by Electrolytic Method. Doctor Thesis, Kyoto University, 1970.
-
3Okino, F.; Kawaguchi, Y.; Touhara, H.; Momota, K.; Nishitani-Gamo, M.; Ando, T.; et al. Preparation of Boron-Doped Semiconducting Diamond Films Using BF3 and the Electrochemical Behavior of the Semiconducting Diamond Electrodes. J. Fluorine, Chem. 2004, 125, 1715-1722.
-
4Tasaka, A.; Morimoto, E.; Mimoto, A.; Inoue, A.; Inaba, M. Measurement of and Thermodynamic Analysis of NiF2/Ni Electrode Potential in a Dehydrated Melt of NH4F·2HF. J. Electrochem. Soc. 2007, 154(11), 172-177.
-
5Morrow, S. I.; Perry, D. D.; Cohen, M. S.; Schienfelder, C Fluorination of Ammonia. J. Am. Chem. Soc. 1960, 82, 5301-5304.
-
1戎非,顾林娟,邱烨静,付德刚,吴巍.掺硼金刚石电极结合二氧化钛光催化阳极氧化降解苯酚(英文)[J].Journal of Southeast University(English Edition),2010,26(3):421-425.
-
2张伟清.西门子公司处理炼油厂和石化厂废碱液的新技术[J].石油炼制与化工,2017,48(1):10-10.
-
3Xiao Hong FANG,Tao ZHU,Dong Mei,QIANG and Yi Liang SUN(Department of Chemistry. Peking University. Beijing 100871,P.R.China).MONITORING ELECTROLYTIC REACTION OF NUCLEAR FAST RED BY HIGH PERFORMANCE CAPILLARY ELECTROPHORESIS[J].Chinese Chemical Letters,1994,5(7):597-600.
-
4杨大荣.关于NH3与NF3分子极性的讨论[J].化学教育,1989,4(4):49-50.
-
5张健琼,贾晓鹏,马红安,任国仲,臧传义,姜一萍.掺硼金刚石的高温高压合成[J].金刚石与磨料磨具工程,2005,25(1):15-17. 被引量:7
-
6刘艳.全氟温室气体NF_3与H自由基脱氟反应机理[J].渭南师范学院学报,2016,31(16):40-44.
-
7陈明娟.电解法生产氯酸盐盐水中硫酸根含量测定方法的探讨[J].福建分析测试,2007,16(2):76-78.
-
8陈鲁倬(编译).激光诱导令石墨转变为金刚石结构[J].科学新闻,2008(18):4-4.
-
9孙阮冰,张健夫.NF_3与NH_3偶极矩反差原因分析[J].周口师专学报,1997,14(2):38-39. 被引量:2
-
10郭丹.超导金刚石[J].科学,2004,56(3):32-32.