通过磁矩判断配合物内外轨型的解题思路

Thoughts of Solving Problems on Judging Internal and External Orbital Type of Complexes by Magnetic Moment

通过磁矩判断配合物内外轨型是一类无机化学中的常见题目。首先通过磁矩推断出未成对电子数,然后根据核外电子的排布原则,结合中心原子(离子)在元素周期表中的位置,推断出配合物的内外轨型。

Judging internal and external orbital type of complexes by magnetic moment is a kind ofcommom titles in inorganic chemistry. At first, the number of unpaired electrons should be judged by magnetic moment, then based on the arrangement principle of extranuclear electrons, internal and external orbital type of complexes may be deduced, combined with the position of central atom （ion） in element periodic table.