摘要
采用一种快速、无模板、低成本的微波辅助水热法在2min内制备了三维花状Co3O4.所用原料均是无机盐.前驱体浓度和尿素的逐渐水解对Co3O4形貌影响很大.制得的花状Co3O4比表面积大,且暴露了(110)高活性指数面,对CO氧化具有较高的催化活性.
3D flowerlike Co304 nanostructures were prepared by a microwave-assisted hydrothermal method, which is a rapid, template-free, and low cost method. The product is obtained in two minutes using all inorganic precursors. The precursor concentration and gradual hy- drolysis of urea determine the morphology of C0304 nanostructures. These flowerlike C0~O4 nanostructures have high surface area and ex- pose largely active (110) planes, leading to relative high catalytic activity in CO oxidation.
出处
《催化学报》
SCIE
CAS
CSCD
北大核心
2012年第8期1334-1339,共6页
基金
国家重点基础研究发展计划(973计划,2009CB930400,2011CB933700)
国家自然科学基金(21121063)~~
关键词
一氧化碳
氧化
四氧化三钴
纳米结构
微波
carbon monoxide
oxidation
cobaltosic oxide
nanostructure
microwave