期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

甲苯选择性催化氧化非均相反应体系研究进展 被引量：2

Research progress of selective oxidation of toluene in heterogeneous liquid phase system
下载PDF
导出
摘要 综述了用于甲苯液相选择性氧化的固体催化剂的研究进展,并对不同的催化剂进行了综合比较。介绍了上述催化剂参与下甲苯氧化的反应机理。指出提高甲苯转化率和高附加值产品的选择性是今后的发展方向。 The research developments of solid catalysts used for toluene oxidation in liquid-phase are reviewed. The properties and performance of these catalysts are compared. The reaction mechanisms of toluene oxidation catalyzed by these catalysts are introduced. It is pointed out that improving toluene conversion and obtaining high selectivity for the products with high added value, such as benzaldehyde and benzayl alcohol, are the development directions in the future.
作者 程婧 佟天下 曾爱武
机构地区 天津大学化学工程联合国家重点实验室
出处 《现代化工》 CAS CSCD 北大核心 2012年第8期11-14,共4页 Modern Chemical Industry
关键词 甲苯 催化氧化 液相 非均相 机理 toluene catalytic oxidation liquid heterogeneous mechanism
分类号 TQ032.4 [化学工程]
  • 相关文献

参考文献28

  • 1Ratnasamy P, Raja R, Srinivas D. Novel, benign, solid catalysts for the oxidation of hydrocarbons [ J ]. Physical and Engineering Sci- ences ,2005,363 ( 1829 ) : 1001 - 1012.
  • 2Lv Jiangang, Shen Yi, Peng Luming, et al. Exclusively selective oxi- dation of toluene to benzaldehyde on ceria nanocubes by molecular oxygen [ J ]. Chemical Communications, 2010,46 ( 32 ) : 5909 - 5911.
  • 3Li Xiaoqiang, Xu Jie, Wang Feng, et al. Direct oxidation of toluene to benzoic acid with molecular oxygen over manganese oxides[ J ]. Catalysis Letters,2006,108 (3/4) : 137 - 140.
  • 4李晓强,徐杰,周利鹏,高进,王峰,陈晨.铜锰双金属氧化物催化的液相甲苯氧化反应(英文)[J].催化学报,2006,27(5):369-371. 被引量：12
  • 5Li Xiaoqiang, Xu Jie, Zhou Lipeng, et al. Liquid-phase oxidation of toluene by molecular oxygen over copper manganese oxides[ J]. Ca- talysis Letters,2006,110 ( 3/4 ) :255 - 260.
  • 6Wang Bo, Mao Wei, Ma Hongzhu. A Mild Simple Method for Liq- uid-Phase Selective Catalytic Oxidation of Toluene with Ozone over CeO2 Promoted Sulfated TiO2 [ J ]. Industrial & Engineering Chem- istry Research ,2009,48 ( 1 ) :440 -445.
  • 7Subrahmanyama Ch, Louis B, Viswanathana B, et al. Synthesis, characterisation and catalytic properties of vanadium substituted mesoporous aluminophosphates [ J ]. Applied Catalysis A : General, 2005,282(1/2) :67 -71.
  • 8Raja R ,Thomas J M, Dreyer V. Benign oxidants and single-site sol- id catalysts for the solvent-free selective oxidation of toluene [ J ]. Catalysis Letters,2006,110 (3/4) : 179 - 183.
  • 9Babranowski K,Dula R,Gasior M,et al. Oxidation of aromatic hy- drocarbons with hydrogen peroxide over Zn, Cu, M-layered double hydroxides [ J ]. Applied Clay Science,2001,18 ( 1/2 ) : 93 - 101.
  • 10Thomas J M, Raja R. Innovations in oxidation catalysis leading to a sustainable society[ J]. Catalysis Today,2006,117 ( 1/2/3 ) :22 - 31.

二级参考文献13

  • 1Sheldon R A,Kochi J K.Metal-Catalyzed Oxidations of Organic Compounds.New York:Academic Press,1981
  • 2Lozar J,Falgayrac G,Savall A.Ind Eng Chem,Res,2001,40(26):6055
  • 3Suresh A K,Sharma M M,Sridhar T.Ind Eng Chem,Res,2000,39(11):3958
  • 4Holtz H D,Gardner L E.US 4 088 823.1978
  • 5Bastock T W,Clark J H,Martin K,Trenbirth B W.Green Chem,2002,4(6):615
  • 6Zhu J,Robertson A,Tsang S C.Chem Commun,2002,(18):2044
  • 7Zhu J,Tsang S C.Catal Today,2003,81(4):673
  • 8Kantam M L,Sreekanth P,Rao K K,Kumar T P,Rao B P C,Choudary B M.Catal Lett,2002,81(3-4):223
  • 9Yoshino Y,Hayashi Y,Iwahama T,Sakaguchi S,Ishii Y.J Org Chem,1997,62(20):6810
  • 10Hutchings G J,Mirzaei A A,Joyner R W,Siddiqui M R H,Taylor S H.Appl Catal A,1998,166(1):143

共引文献11

同被引文献33

  • 1刘伟华,张同来,张建国,孙远华,张水光.甲苯氧化制苯甲醛技术进展[J].化工生产与技术,2004,11(3):24-28. 被引量：13
  • 2曹志红,刘文明,康永红.催化合成苯甲醛催化剂研究进展[J].化工中间体,2006,2(11):2-5. 被引量：6
  • 3戴琳,王志祥,史益强.苯甲醛绿色生产工艺研究进展[J].化工时刊,2006,20(11):71-73. 被引量：1
  • 4刘文明,曹志红,项学明.Ce-OMS-2催化剂气相催化氧化甲苯制苯甲醛[J].石油化工,2007,36(7):716-720. 被引量：9
  • 5Vicente F S, Jordi M S, Josep-manuel P, et al. Effects of nitrogen source and empty bed residence time on the re- moval of styrene gaseous emissions by biotfickling filtra- tion [ J ]. Bioprocess Biosyst Eng, 2011,34 (7) : 859 -867.
  • 6Lv J G, Shen Y, Peng L M, et al. Exclusively selective ox- idation of toluene to benzaldehyde on celia nanocubes by molecular oxygen [ J ]. Chem Comm, 2010,46 (32) : 5 909- 5 911.
  • 7Kantam M L, Sreckanth P, Rao K K, et al. An improved process for selective liquid-phase air oxidation of toluene [ J]. Catal Lett,2002,81 (3-4) :223-232.
  • 8Bahranowski K, Dula R, Gasior M, et al. Oxidation of aro- matic hydrocarbons with hydrogen peroxide over Zn, Cu, Al-layered double hydroxid [ J ]. Appl Clay Sci, 2001,18 (1/2) :93-101.
  • 9Thomas J M, Raja R. Innovations in oxidation catalysis leading to a sustainable society [ J ]. Catal Today, 2006, 117(1-2) :22-31.
  • 10Wang M, Chen C, Zhang Q H, et al. Phenylmodification of Mn-containing mesopomus silica and catalytic oxidation of toluen [ J ]. Chem Technol Biotechnol,2010,85 (2) :283 - 287.

引证文献2

现代化工
2012年 第8期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部