期刊文献+

Electrocatalytic determination of L-cysteine using a modified carbon nanotube paste electrode:Application to the analysis of some real samples 被引量:5

Electrocatalytic determination of L-cysteine using a modified carbon nanotube paste electrode:Application to the analysis of some real samples
原文传递
导出
摘要 The electrooxidation of L-cysteine(L-Cys) was studied using a benzoylferrocene(BF) modified multi-wall carbon nanotube paste electrode(BFCNPE) using cyclic voltammetry(CV),square wave voltammetry(SWV) and chronoamperometry(CHA).Under optimum pH in CV the oxidation of L-Cys occurs at a potential about 215 mV less positive than that at the surface of unmodified carbon paste electrode.The catalytic oxidation peak currents were dependent on the L-Cys concentration and a linear calibration curve was obtained in the range 0.7-350.0 mmol/L of L-Cys with SWV method.The detection limit(3s) was determined as 0.1 mmol/L.This method was also used for the determination of L-Cys in some real samples. The electrooxidation of L-cysteine(L-Cys) was studied using a benzoylferrocene(BF) modified multi-wall carbon nanotube paste electrode(BFCNPE) using cyclic voltammetry(CV),square wave voltammetry(SWV) and chronoamperometry(CHA).Under optimum pH in CV the oxidation of L-Cys occurs at a potential about 215 mV less positive than that at the surface of unmodified carbon paste electrode.The catalytic oxidation peak currents were dependent on the L-Cys concentration and a linear calibration curve was obtained in the range 0.7-350.0 mmol/L of L-Cys with SWV method.The detection limit(3s) was determined as 0.1 mmol/L.This method was also used for the determination of L-Cys in some real samples.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2012年第8期981-984,共4页 中国化学快报(英文版)
关键词 L-CYSTEINE Carbon paste electrode Carbon nanotubes VOLTAMMETRY L-Cysteine Carbon paste electrode Carbon nanotubes Voltammetry
  • 相关文献

参考文献1

二级参考文献11

  • 1W.A.Gahl,Eur.J.Pediatr.162(2003) S38.
  • 2CM.Pfeiffer,Z.Fazili,L.McCoy,et al.Clin.Chem.50(2004) 423.
  • 3D.Hoegger,P.Morier,C.Vollet,et al.Anal.Bioanal.Chem.387(2007) 267.
  • 4Z.Omran,G.Kay,E.E.Hector,et al.Bioorg.Med.Chem.Lett.21(2011) 2502.
  • 5M.A.Khalilzadeh,H.Karimi-Maleh,A.Amiri,et al.Chin.Chem.Lett.21(2010) 1467.
  • 6J.B.Raoof,R.Ojani,H.Karimi-Maleh,Chin.Chem.Lett.21(2010) 1462.
  • 7H.Beitollahi,H.Karimi-Maleh,H.Khabazzadeh,Anal.Chem.80(2008) 9848.
  • 8A.J.Bard,L.R.Faulkner,Electrochemical Methods,John Wiley and Sons,New York,2001,p.163.
  • 9Z.Galus,Fundumentals of Electrochemical Analysis,Ellis Horwood,New York,1976.
  • 10A.A.Ensafi,H.Karimi-Maleh,Electroanalysis 22(2010) 2558.

共引文献5

同被引文献60

  • 1孟紫强,刘玉香.二氧化硫吸入对小鼠脑、心、肾、睾丸超微结构的影响[J].环境科学学报,2006,26(1):130-136. 被引量:26
  • 2许金钩,王尊本.荧光分析法[M],北京:科学出版社,2006
  • 3贾存江,王英燕,赵丽丽.L-半胱氨酸的生产方法及应用进展[J].齐鲁药事,2007,26(9):553-555. 被引量:24
  • 4Ni Y, Liu G, Kokot S. Fluorescence spectrometric study on the in- teractions of isoprocarb and sodium 2-isopropylphenate with bo- vine serum albumin[J]. Talanta, 2008,76 (3): 513-521.
  • 5Zhang P J, Lan P, Ma Y N, et al. Spectroscopic investigation on the interaction of Cr(VI) with bovine serum albumin[J]. J Bio- them Mol Toxieol,2012,26(2) : 54-59.
  • 6Ross P D, Subramanian S. Thermodynamics of protein associa- tion reactions : Forces contributing to stability[J]. Biochemistry, 1981 ,20(11) :3096-3102.
  • 7Mu Y,Lin J, Liu R. Interaction of sodium benzoate with trypsin by spectroscopic techniques[J]. Spectrochim Acta A:Mol Biomol Spectrosc, 2011,83(1):130-135.
  • 8Klajnert B,Bryszewska M. Fluorescence studies on PAMAM de- ndrimers interactions with bovine serum albumin[J]. Bioelectro- chemistry, 2002,55 (1-2) : 33-35.
  • 9JP.
  • 10Beitollahi HKarimi‐Maleh HKhabazzadeh HAnalytical Chemistry.

引证文献5

二级引证文献8

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部