An acentric lanthanide-formate complex: synthesis, structure, ferroelectric and magnetic properties

An acentric lanthanide-formate complex: synthesis, structure, ferroelectric and magnetic properties

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摘要 An acentric complex, [Sm（HCOO）3]n （1）, was hydrothermally synthesized and characterized by single-crystal X-ray diffraction, IR, and element analysis. Complex 1 crystallized in the rhombohedral system with acentric space group R3m and afforded a three-dimensional （3D） structure. Interestingly, ferroelectric and magnetic studies revealed that complex 1 demonstrated both ferroelectric and antiferromagnetic properties. An acentric complex, [Sm（HCOO）3]n （1）, was hydrothermally synthesized and characterized by single-crystal X-ray diffraction, IR, and element analysis. Complex 1 crystallized in the rhombohedral system with acentric space group R3m and afforded a three-dimensional （3D） structure. Interestingly, ferroelectric and magnetic studies revealed that complex 1 demonstrated both ferroelectric and antiferromagnetic properties.

作者冯丹车云霞郑吉民

机构地区 Department of Chemistry

出处《Journal of Rare Earths》 SCIE EI CAS CSCD 2012年第8期798-801,共4页 稀土学报（英文版）

基金 Project supported by National Natural Science Foundation of China(50872057)

关键词 FERROELECTRIC MAGNETIC LANTHANIDE formic acid rare earths ferroelectric magnetic lanthanide formic acid rare earths

分类号 O621.2 [理学—有机化学]

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参考文献11

1张文臣,赵睿,方以坤,周鸣鸽,朱明刚,李卫.Effect of Sm-rich liquid phase on magnetic properties and microstructures of sintered 2:17-type Sm-Co magnet[J].Journal of Rare Earths,2011,29(10):934-938. 被引量：5
2Yamazaki Y,Miyasaka S,Kaneko Y,He J P,Arima T,Tokura Y.Magnetic reversal of the ferroelectric polarization in a mul-tiferroic spinel oxide[].Physics Review Letters.2006
3Wang C F,Gu Z G,Lu X M,Zuo J L,You X Z.Ferroelectric heterobimetallic clusters with ferromagnetic interactions[].Inorganic Chemistry.2008
4Ye Q,Fu D W,Tian H,Xiong R G,Chan P W H,Huang S D.Multiferroic homochiral metal-organic framework[].Inorganic Chemistry.2008
5Xu Y,Ding S H,Zhou G P,Liu Y G.Samarium (III)formate[].Acta CrystE.2006
6Cui H B,Wang Z M,Kazuyuki Takahashi,Yoshinori Okano,Hayao Kobayashi,Akiko Kobayashi.Ferroelectric porous molecular crystal [Mn3 (HCOO)6] (C2H5OH),exhibiting ferri-magnetic transition[].Journal of the American Chemical Society.2006
7LIN X,LIU T,LIN J, et al.Syntheses and characterizations of two new pillared-layer coordinationpolymers constructed from lanthanides and mixed O-donor ligands[].Inorganic ChemistryCommunications.2010
8Bünzli,J.-C. G.,Bünzli,J.-C. G.,Choppin,G. R. Lanthanide Probes in Life, Chemical and Earth Sciences . 1989
9Tian XL,Li J,Chen K,Han J,Pan SL,Wang YJ,Fan XY,Li F,Zhou ZX.Nearly monodisperse ferroelectric BaTiO 3 hollow nanoparticles: Size-related solid evacuation in ostwald-ripening-induced hollowing process[].Crystal Growth and Design.2010
10Rao C. N. R,Serrao C. R.New routes to multiferroics[].J Chem Mater.2007

二级参考文献19

1Ya. G. Bogatin,E. G. Povolotskii.Crystal structure and magnetic properties of SmCo5 permanent magnets produced by deformation sintering[J]. Soviet Powder Metallurgy and Metal Ceramics . 1981 (1)
2Sugimoto S.Current status and recent topics of rare-earth permanent magnets. Journal of Physics . 2011
3Guo Zhaohui,Pan Wei,Li Wei.Sm(Co,Fe,Cu,Zr)z sintered magnets with a maximum operating temperature of 500 oC. Journal of Magnetism and Magnetic Materials . 2006
4Goll D,Kronmuller H,Stadelmaier H H.Micromagnetism and the microstructure of high temperature permanent magnets. Journal of Applied Physics . 2004
5Wohlfarth E P.Ferromagnetic materials: a handbook on the properties of magnetically ordered substances. . 1980
6Tang W,Zhang Y,Hadjipanayis G C.Microstructure and magnetic properties of Sm (CobalFexCu0.128Zr0.02)7.0 magnets with Fe substitution. Journal of Magnetism and Magnetic Materials . 2000
7Peng Long,Yang Qiuhui,Zhang Huaiwu,Xu Guangliang,Zhang Ming,Wang Jingdong.Rare earth permanent magnets Sm2 (Co,Fe,Cu,Zr)17 for high temperature applications. Scripta Materialia . 2008
8Liu Sam,Potts Gregory,Doyle George,Yang Jie,Kuhl Edward G,Chen C,Marlin S Walmer,Michael H Walmer.Effect of Z value on high temperature performance of Sm (Co,Fe,Cu,Zr)z with z=7.14-8.10. IEEE Transactions on Magnetics . 2000
9Livingston J D,Martin D L.Microstructure of aged (Co,Cu,Fe)7Sm magnets. Journal of Applied Physics . 1977
10Luo J,Guo Y Q,Li W.Effects of Cu on crystallographic and magnetic properties of Sm(Co,Cu)7. Journal of Physics . 2003

共引文献4

1Guanghui Yan,Zhuang Liu,Yanping Feng,Weixing Xia,Chaoyue Zhang,Guangqing Wang,Aru Yan.Zirconium content induced mitigation of mechanical anisotropy in 2:17 type SmCo magnets[J].Journal of Rare Earths,2020,38(2):182-187. 被引量：6
2Wei Sun,Ming-Gang Zhu,Yi-Kun Fang,Wei Pan,Man-Long Xia,Wei Li.Microstructure and magnetic properties of sintered CeCo_(4.3252-x)Cu_(0.675)Fe_x magnets[J].Rare Metals,2015,34(3):164-167. 被引量：1
3Donghui Liu,Fei Niu,Xiaolin Zhang,Yuning Meng,Youming Yang.Fabrication of SmCo_(5) alloy via cobalt-induced calciothermic reduction and magnetic properties of its ribbon[J].Journal of Rare Earths,2021,39(5):572-578. 被引量：1
4Kuikui Songa,Wei Suna,Yikun Fang,Shuai Wang,Nengjun Yu,Meiling Zhang,Minggang Zhu,Wei Li.Optimization of microstructures and magnetic properties of Sm(Co_(bal)Fe_(0.227)Cu_(0.07)Zr_(0.023))_(7.6) magnets by sintering treatment[J].Journal of Rare Earths,2019,37(2):171-177. 被引量：12

1ZHANG, XY,FURUKAWA, TK.Dielectric Relaxations in Ferroelectric Copolymer VDF(73)/TrFE(27)[J].Journal of Materials Science & Technology,1995,11(1):31-37.
2靳素荣,张联盟,柳士忠,姚礼峰,胡学雷,赵卫锋.Organic-inorganic Hybrid Materials Based on Molybdophosphate and Organic Polyammonium[J].Chinese Journal of Chemistry,2005,23(8):1123-1126. 被引量：3
3Naomi Matsuura,Harry E. Ruda.Highly-Ordered Ferroelectric Photonic Crystals[J].光学学报,2003,23(S1):149-150.
4Magnetic Properties of Heteropoly Complexes α-Na_(m)H_(n)[GaW_(9)M_(3)(H_(2)O)_(3)O_(37)]·16H_(2)O(M=Co(Ⅱ),Mn(Ⅱ),Cr(Ⅲ))[J].Chemical Research in Chinese Universities,1997,13(4):78-81.
5范婧,董新伟,宋友,王克锋,刘俊明,江向平.Ferrimagnetism and abnormal spin lattice coupling in dilute magnetic ferroelectric (Bi_(0.46) Na_(0.46) Ba_(0.08))TiO_3:Co[J].Chinese Physics B,2011,20(2):487-494.
6周金鑫.元素周期表的终点在哪里[J].新课程（中学）,2009(1):88-88.
7Lu Changwei,Xi Tonggeng,Yang Xuehua,Chen Yunxian,Xu Yibin,Dong Xianlin Duan Lian(Shanghai Institute of Ceramics, Chinese Academy of Sciences Shanghai 200050).Investigation　on　Phase　Transition　of　Ferroelectric　Ceramics　of　Lead　Titanate─Zirconate　Doped　with　Niobium　and　Tin─Substituted　Lead　Titanate─Zirconate　by　DTA，DSC　and　PRD[J].化学世界,1996,37(S1):229-231.
8李小明,王芳,赵昆,赵嵩卿.Ultraviolet laser-induced photovoltaic effects in miscut ferroelectric LiNbO_3 single crystals[J].Chinese Physics B,2010,19(7):559-562.
9XIAO YaoMing,WU JiHuai,LI QingHua,XIE GuiXiang,YUE GenTian,YE HaiFeng,LAN Zhang,HUANG MiaoLiang & LIN JianMing Englineering Research Center of Environment-Friendly Functional Materials,Minsitry of Education,China,The Key Laboratory for Functional Materials of Fujian Higher Education,Institute of Materials Physical Chemistry,Huaqiao University,Quanzhou 362021,China.Preparation of photoanode and its application to flexible dye-sensitized solar cells[J].Chinese Science Bulletin,2010,55(10):980-985. 被引量：10
10李衡峰,杨永刚,闻建勋.Synthesis and mesomorphic properities of some ferroelectric liquid crystals of lactate[J].Chinese Journal of Chemistry,2000,18(6):900-909.

Journal of Rare Earths

2012年第8期

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An acentric lanthanide-formate complex: synthesis, structure, ferroelectric and magnetic properties

参考文献11

二级参考文献19

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